DOI: 10.1063/1.464018. Photogeneration of ions via delocalized charge transfer states. II. HX2− (X=Cl,Br,I) in rare gas matrices

Photogeneration of ions via delocalized charge transfer states. II. HX2− (X=Cl,Br,I) in rare gas matrices

10.1063/1.464018

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Photolysis of HX (X=Cl,Br,I) doped rare gas matrices at excitation energies well below direct ionization of the solids is shown to yield efficient formation of hydrogen bihalide anions, HX2−. The formation dynamics of these ions is ascribed to a charge separation process initiated by optical access of the delocalized charge transfer states. The vibrational spectra of HX2− are presented and compared with previous work on M+⋅⋅⋅(HX2)− ion pairs, and the isoelectronic triatomic rare gas hydride cations.

Bibliography

RÃ¤sÃ¤nen, M., Seetula, J., & Kunttu, H. (1993). Photogeneration of ions via delocalized charge transfer states. II. HX2â (X=Cl,Br,I) in rare gas matrices. The Journal of Chemical Physics, 98(5), 3914â3918.

Authors 3

Markku Räsänen (first)
Jorma Seetula (additional)
Henrik Kunttu (additional)

References 22 Referenced 46

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{'key': '2024020705272091800_r13', 'first-page': '5917', 'volume': '87', 'year': '1987', 'journal-title': 'Chem. Phys. Lett.'} / Chem. Phys. Lett. (1987)
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{'key': '2024020705272091800_r17'}
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:44 a.m.)
Deposited	1 year, 6 months ago (Feb. 7, 2024, 3:51 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 3:33 a.m.)
Issued	32 years, 6 months ago (March 1, 1993)
Published	32 years, 6 months ago (March 1, 1993)
Published Print	32 years, 6 months ago (March 1, 1993)

Funders 0

None

BibTeX

@article{R_s_nen_1993, title={Photogeneration of ions via delocalized charge transfer states. II. HX2− (X=Cl,Br,I) in rare gas matrices}, volume={98}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.464018}, DOI={10.1063/1.464018}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Räsänen, Markku and Seetula, Jorma and Kunttu, Henrik}, year={1993}, month=mar, pages={3914–3918} }

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