DOI: 10.1063/1.463822. Vibrational energy redistribution and relaxation in the photoisomerization of <i>cis</i>-stilbene [Penn]

Vibrational energy redistribution and relaxation in the photoisomerization of cis-stilbene

10.1063/1.463822

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Trans-stilbene photoproduces appearing from the photoisomerization of cis-stilbene within 150 fs are observed to be vibrationally hot, but with a nonthermal population distribution. The product electronic spectrum depends on the incident photon energy. Clearly, intramolecular vibrational energy redistribution is not ultrafast.

Bibliography

Sension, R. J., Szarka, A. Z., & Hochstrasser, R. M. (1992). Vibrational energy redistribution and relaxation in the photoisomerization of cis-stilbene. The Journal of Chemical Physics, 97(7), 5239â5242.

Authors 3

Roseanne J. Sension (first)
Arpad Z. Szarka (additional)
Robin M. Hochstrasser (additional)

References 23 Referenced 66

10.1063/1.459168 / J. Chem. Phys. (1990)
10.1063/1.459252 / J. Chem. Phys. (1990)
10.1063/1.459707 / J. Chem. Phys. (1990)
10.1002/bbpc.19910950306 / Ber. Bunsenges. Phys. Chem. (1991)
10.1021/j100161a004 / J. Phys. Chem. (1991)
10.1021/j100178a026 / J. Phys. Chem. (1991)
{'key': '2024021013224002300_r7', 'first-page': '3359', 'volume': '96', 'year': '1992', 'journal-title': 'J. Phys. Chem.'} / J. Phys. Chem. (1992)
{'key': '2024021013224002300_r8'}
{'key': '2024021013224002300_r9'}
10.1146/annurev.pc.42.100191.000503 / Annu. Rev. Phys. Chem. (1991)
{'key': '2024021013224002300_r11'}
10.1063/1.447884 / J. Chem. Phys. (1984)
10.1063/1.449765 / J. Chem. Phys. (1985)
10.1063/1.430265 / J. Chem. Phys. (1975)
10.1021/j100350a020 / J. Phys. Chem. (1989)
{'key': '2024021013224002300_r16'}
{'key': '2024021013224002300_r17', 'first-page': '6075', 'volume': '95', 'year': '1991', 'journal-title': 'J. Phys. Chem.'} / J. Phys. Chem. (1991)
{'key': '2024021013224002300_r18'}
{'key': '2024021013224002300_r19', 'first-page': '662', 'year': '1967', 'journal-title': 'J. Chem. Soc. (B)'} / J. Chem. Soc. (B) (1967)
{'key': '2024021013224002300_r20', 'first-page': '1930', 'year': '1974', 'journal-title': 'J. Chem. Soc. Perkin II'} / J. Chem. Soc. Perkin II (1974)
{'key': '2024021013224002300_r21'}
10.1021/ja00167a086 / J. Am. Chem. Soc. (1990)
10.1021/ja00226a065 / J. Am. Chem. Soc. (1988)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:22 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 9:59 a.m.)
Indexed	5 months ago (April 1, 2025, 6:04 a.m.)
Issued	32 years, 11 months ago (Oct. 1, 1992)
Published	32 years, 11 months ago (Oct. 1, 1992)
Published Print	32 years, 11 months ago (Oct. 1, 1992)

Funders 0

None

BibTeX

@article{Sension_1992, title={Vibrational energy redistribution and relaxation in the photoisomerization of cis-stilbene}, volume={97}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.463822}, DOI={10.1063/1.463822}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Sension, Roseanne J. and Szarka, Arpad Z. and Hochstrasser, Robin M.}, year={1992}, month=oct, pages={5239–5242} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        4,
        1
      ]
    ],
    "date-time": "2025-04-01T10:04:17Z",
    "timestamp": 1743501857817
  },
  "reference-count": 23,
  "publisher": "AIP Publishing",
  "issue": "7",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1992,
        10,
        1
      ]
    ]
  },
  "abstract": "<jats:p>Trans-stilbene photoproduces appearing from the photoisomerization of cis-stilbene within 150 fs are observed to be vibrationally hot, but with a nonthermal population distribution. The product electronic spectrum depends on the incident photon energy. Clearly, intramolecular vibrational energy redistribution is not ultrafast.</jats:p>",
  "DOI": "10.1063/1.463822",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T12:22:38Z",
    "timestamp": 1027686158000
  },
  "page": "5239-5242",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 66,
  "title": "Vibrational energy redistribution and relaxation in the photoisomerization of <i>cis</i>-stilbene",
  "prefix": "10.1063",
  "volume": "97",
  "author": [
    {
      "given": "Roseanne J.",
      "family": "Sension",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104"
        }
      ]
    },
    {
      "given": "Arpad Z.",
      "family": "Szarka",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104"
        }
      ]
    },
    {
      "given": "Robin M.",
      "family": "Hochstrasser",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024021013224002300_r1",
      "doi-asserted-by": "crossref",
      "first-page": "1041",
      "DOI": "10.1063/1.459168",
      "volume": "93",
      "year": "1990",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021013224002300_r2",
      "doi-asserted-by": "crossref",
      "first-page": "8658",
      "DOI": "10.1063/1.459252",
      "volume": "93",
      "year": "1990",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021013224002300_r3",
      "doi-asserted-by": "crossref",
      "first-page": "9185",
      "DOI": "10.1063/1.459707",
      "volume": "93",
      "year": "1990",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021013224002300_r4",
      "doi-asserted-by": "crossref",
      "first-page": "248",
      "DOI": "10.1002/bbpc.19910950306",
      "volume": "95",
      "year": "1991",
      "journal-title": "Ber. Bunsenges. Phys. Chem."
    },
    {
      "key": "2024021013224002300_r5",
      "doi-asserted-by": "crossref",
      "first-page": "2946",
      "DOI": "10.1021/j100161a004",
      "volume": "95",
      "year": "1991",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021013224002300_r6",
      "doi-asserted-by": "crossref",
      "first-page": "10380",
      "DOI": "10.1021/j100178a026",
      "volume": "95",
      "year": "1991",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021013224002300_r7",
      "first-page": "3359",
      "volume": "96",
      "year": "1992",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021013224002300_r8"
    },
    {
      "key": "2024021013224002300_r9"
    },
    {
      "key": "2024021013224002300_r10",
      "doi-asserted-by": "crossref",
      "first-page": "83",
      "DOI": "10.1146/annurev.pc.42.100191.000503",
      "volume": "42",
      "year": "1991",
      "journal-title": "Annu. Rev. Phys. Chem."
    },
    {
      "key": "2024021013224002300_r11"
    },
    {
      "key": "2024021013224002300_r12",
      "doi-asserted-by": "crossref",
      "first-page": "1552",
      "DOI": "10.1063/1.447884",
      "volume": "81",
      "year": "1984",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021013224002300_r13",
      "doi-asserted-by": "crossref",
      "first-page": "5000",
      "DOI": "10.1063/1.449765",
      "volume": "83",
      "year": "1985",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021013224002300_r14",
      "doi-asserted-by": "crossref",
      "first-page": "214",
      "DOI": "10.1063/1.430265",
      "volume": "62",
      "year": "1975",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021013224002300_r15",
      "doi-asserted-by": "crossref",
      "first-page": "5124",
      "DOI": "10.1021/j100350a020",
      "volume": "93",
      "year": "1989",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021013224002300_r16"
    },
    {
      "key": "2024021013224002300_r17",
      "first-page": "6075",
      "volume": "95",
      "year": "1991",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021013224002300_r18"
    },
    {
      "key": "2024021013224002300_r19",
      "first-page": "662",
      "year": "1967",
      "journal-title": "J. Chem. Soc. (B)"
    },
    {
      "key": "2024021013224002300_r20",
      "first-page": "1930",
      "year": "1974",
      "journal-title": "J. Chem. Soc. Perkin II"
    },
    {
      "key": "2024021013224002300_r21"
    },
    {
      "key": "2024021013224002300_r22",
      "doi-asserted-by": "crossref",
      "first-page": "4580",
      "DOI": "10.1021/ja00167a086",
      "volume": "112",
      "year": "1990",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024021013224002300_r23",
      "doi-asserted-by": "crossref",
      "first-page": "6269",
      "DOI": "10.1021/ja00226a065",
      "volume": "110",
      "year": "1988",
      "journal-title": "J. Am. Chem. Soc."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/97/7/5239/19002161/5239_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/97/7/5239/19002161/5239_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T14:59:40Z",
    "timestamp": 1707577180000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/97/7/5239/799385/Vibrational-energy-redistribution-and-relaxation"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1992,
        10,
        1
      ]
    ]
  },
  "references-count": 23,
  "journal-issue": {
    "issue": "7",
    "published-print": {
      "date-parts": [
        [
          1992,
          10,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.463822",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1992,
        10,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1992,
        10,
        1
      ]
    ]
  }
}