DOI: 10.1063/1.463596. Solute–solute correlations in infinitely dilute supercritical mixtures

Solute–solute correlations in infinitely dilute supercritical mixtures

10.1063/1.463596

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Asymptotic expressions for the solute–solute pair correlation integral and for the limiting slope of the composition dependence of the solute’s activity coefficient are derived for the situation in which the solvent’s critical point is approached while the mixture is kept at infinite dilution. Both quantities diverge to plus infinity and scale as the solvent’s compressibility, with prefactors that depend on the temperature, solvent density, and the infinite dilution limit of the solute–solvent direct correlation function integral.

Bibliography

Debenedetti, P. G., & Chialvo, A. A. (1992). Soluteâsolute correlations in infinitely dilute supercritical mixtures. The Journal of Chemical Physics, 97(1), 504â507.

Authors 2

Pablo G. Debenedetti (first)
Ariel A. Chialvo (additional)

References 37 Referenced 28

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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:22 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 9:42 a.m.)
Indexed	11 months, 2 weeks ago (Sept. 3, 2024, 3:26 p.m.)
Issued	33 years, 1 month ago (July 1, 1992)
Published	33 years, 1 month ago (July 1, 1992)
Published Print	33 years, 1 month ago (July 1, 1992)

Funders 0

None

BibTeX

@article{Debenedetti_1992, title={Solute–solute correlations in infinitely dilute supercritical mixtures}, volume={97}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.463596}, DOI={10.1063/1.463596}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Debenedetti, Pablo G. and Chialvo, Ariel A.}, year={1992}, month=jul, pages={504–507} }

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