DOI: 10.1063/1.462330. Evidence for polyicosahedral structure in ammoniated iron, cobalt, and nickel clusters

Evidence for polyicosahedral structure in ammoniated iron, cobalt, and nickel clusters

10.1063/1.462330

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Experimental evidence is presented that small (19- to 34-atom) clusters of iron, cobalt, and nickel tend to adopt polyicosahedral structure when saturated with ammonia. Clusters in the polyicosahedral series (having 19, 23, 26, 29, 32, and 34 atoms) often saturate with 12 NH3 molecules, the expected number for polyicosahedral structure. Other clusters in this size range, which do not have an obvious number of NH3 binding sites, generally do not show a clear saturation. Adsorbate-induced structural changes are also seen, and suggest that for larger clusters in the series there is a transformation to an alternate structure that binds more than 12 NH3 molecules.

Bibliography

Parks, E. K., Winter, B. J., Klots, T. D., & Riley, S. J. (1992). Evidence for polyicosahedral structure in ammoniated iron, cobalt, and nickel clusters. The Journal of Chemical Physics, 96(11), 8267â8274.

Authors 4

E. K. Parks (first)
B. J. Winter (additional)
T. D. Klots (additional)
S. J. Riley (additional)

References 18 Referenced 69

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10.1016/0009-2614(84)85343-9 / Chem. Phys. Lett. (1984)
10.1063/1.449219 / J. Chem. Phys. (1985)
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{'key': '2024021012391679500_r7'}
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{'key': '2024021012391679500_r10'}
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:21 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 9:18 a.m.)
Indexed	1 year ago (Aug. 2, 2024, 8:37 a.m.)
Issued	33 years, 2 months ago (June 1, 1992)
Published	33 years, 2 months ago (June 1, 1992)
Published Print	33 years, 2 months ago (June 1, 1992)

Funders 0

None

BibTeX

@article{Parks_1992, title={Evidence for polyicosahedral structure in ammoniated iron, cobalt, and nickel clusters}, volume={96}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.462330}, DOI={10.1063/1.462330}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Parks, E. K. and Winter, B. J. and Klots, T. D. and Riley, S. J.}, year={1992}, month=jun, pages={8267–8274} }

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