DOI: 10.1063/1.462280. Solvent-electronic state interactions measured from the glassy to the liquid state. I. Ultrafast transient and permanent hole burning in glycerol

Solvent-electronic state interactions measured from the glassy to the liquid state. I. Ultrafast transient and permanent hole burning in glycerol

10.1063/1.462280

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Picosecond transient and permanent hole burning spectroscopies are used to study the interaction between glycerol and the electronic states of the nonpolar solute dimethyl-s-tetrazine. Variable temperature measurements from the low temperature glass into the fluid region have identified a phonon-modulated interaction in agreement with a previous hypothesis [J. Chem. Phys. 94, 5787 (1991)]. However, this mechanism alone cannot account for the magnitude of the subpicosecond line broadening seen at room temperature. A second relaxation mechanism is identified, which is connected to the structural coordinates involved in the glass transition and reaches subpicosecond relaxation times at room temperature.

Bibliography

Yu, J., & Berg, M. (1992). Solvent-electronic state interactions measured from the glassy to the liquid state. I. Ultrafast transient and permanent hole burning in glycerol. The Journal of Chemical Physics, 96(12), 8741â8749.

Authors 2

Jongwan Yu (first)
Mark Berg (additional)

References 40 Referenced 45

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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:21 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 9:29 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 5:57 a.m.)
Issued	33 years, 2 months ago (June 15, 1992)
Published	33 years, 2 months ago (June 15, 1992)
Published Print	33 years, 2 months ago (June 15, 1992)

Funders 0

None

BibTeX

@article{Yu_1992, title={Solvent-electronic state interactions measured from the glassy to the liquid state. I. Ultrafast transient and permanent hole burning in glycerol}, volume={96}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.462280}, DOI={10.1063/1.462280}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Yu, Jongwan and Berg, Mark}, year={1992}, month=jun, pages={8741–8749} }

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