DOI: 10.1063/1.461958. A lattice model description of amphiphilic mixtures. I. Equilibrium properties

A lattice model description of amphiphilic mixtures. I. Equilibrium properties

10.1063/1.461958

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A three-component lattice model with unit-vector orientations at the lattice sites is presented. The model describes ternary mixtures of oil, water, and amphiphile, and in particular the microemulsion phase. The phase diagram of the model is derived using mean-field theory and simulation. It is shown that the results of Monte Carlo simulations of sufficiently large systems show remarkable agreement with experiment. In particular, the present model reproduces the mesoscopic order of the microemulsion phase. The structure of the microemulsion is understood in terms of the liquid-crystalline phases adjacent to it on the phase diagram and the nature of the phase transitions that occur between them. The behavior of the system when the ratio of oil to water is changed is investigated and the percolation threshold is described. A method for carrying out dynamical simulations is discussed.

Bibliography

Gunn, J. R., & Dawson, K. A. (1992). A lattice model description of amphiphilic mixtures. I. Equilibrium properties. The Journal of Chemical Physics, 96(4), 3152â3169.

Authors 2

John R. Gunn (first)
K. A. Dawson (additional)

References 40 Referenced 21

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:32 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 9:11 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 3:32 a.m.)
Issued	33 years, 6 months ago (Feb. 15, 1992)
Published	33 years, 6 months ago (Feb. 15, 1992)
Published Print	33 years, 6 months ago (Feb. 15, 1992)

Funders 0

None

BibTeX

@article{Gunn_1992, title={A lattice model description of amphiphilic mixtures. I. Equilibrium properties}, volume={96}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.461958}, DOI={10.1063/1.461958}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Gunn, John R. and Dawson, K. A.}, year={1992}, month=feb, pages={3152–3169} }

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