DOI: 10.1063/1.461871. The microwave spectrum of the CH2N radical in the <i>X</i>̃ 2<i>B</i>2 ground electronic state

The microwave spectrum of the CH2N radical in the X̃ 2B2 ground electronic state

10.1063/1.461871

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The rotational spectral lines of the CH2N radical in the 2uBd2d ground electronic state are detected by using a source-modulation microwave spectrometer. The radical is produced in a glow discharge plasma of a gaseous mixture of CH4 and N2. In total, 181 fine and hyperfine components of the rotational transitions with N=1–0 to N=5–4 are observed in the frequency region between 73 and 370 GHz. They are analyzed to obtain the molecular constants including hyperfine interaction constants for the H and N nuclei. The molecular structure and the spin density of CH2N are determined from the obtained molecular constants.

Bibliography

Yamamoto, S., & Saito, S. (1992). The microwave spectrum of the CH2N radical in the XÌâ2B2 ground electronic state. The Journal of Chemical Physics, 96(6), 4157â4162.

Authors 2

Satoshi Yamamoto (first)
Shuji Saito (additional)

References 46 Referenced 47

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:21 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 9:02 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 5:21 a.m.)
Issued	33 years, 5 months ago (March 15, 1992)
Published	33 years, 5 months ago (March 15, 1992)
Published Print	33 years, 5 months ago (March 15, 1992)

Funders 0

None

BibTeX

@article{Yamamoto_1992, title={The microwave spectrum of the CH2N radical in the X̃ 2B2 ground electronic state}, volume={96}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.461871}, DOI={10.1063/1.461871}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Yamamoto, Satoshi and Saito, Shuji}, year={1992}, month=mar, pages={4157–4162} }

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