DOI: 10.1063/1.461864. Direct infrared and visible absorption spectroscopy of stoichiometric and nonstoichiometric clusters of indium phosphide

Direct infrared and visible absorption spectroscopy of stoichiometric and nonstoichiometric clusters of indium phosphide

10.1063/1.461864

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Resonant two-color and one-color photodissociation spectroscopy is performed on neutral InxPy clusters with x+y=5 to 14 atoms. Absorption spectra of 29 different InxPy clusters are obtained for excitation energies between 0.84 and 1.84 eV. The absorption behavior is qualitatively similar for all of these clusters. An optical-gap-like absorption feature is observed at the blue end of the spectra, particularly for clusters which contain an even number of atoms. This feature shifts as a function of cluster size, but has an onset close to the band gap of bulk crystalline InP. Weaker absorptions are observed tailing to the red. A distinct absorption peak is also observed near the bulk InP band band gap for odd-numbered clusters with a stoichiometry of Inx+3Px. An empirical fitting of the low energy absorption tails reveals a correlation between the optical behaviors of these tiny clusters and amorphous semiconductors.

Bibliography

Rinnen, K.-D., Kolenbrander, K. D., DeSantolo, A. M., & Mandich, M. L. (1992). Direct infrared and visible absorption spectroscopy of stoichiometric and nonstoichiometric clusters of indium phosphide. The Journal of Chemical Physics, 96(6), 4088â4101.

Authors 4

K.-D. Rinnen (first)
K. D. Kolenbrander (additional)
A. M. DeSantolo (additional)
M. L. Mandich (additional)

References 42 Referenced 43

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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:21 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 9:12 a.m.)
Indexed	1 year ago (Aug. 22, 2024, 1:48 a.m.)
Issued	33 years, 5 months ago (March 15, 1992)
Published	33 years, 5 months ago (March 15, 1992)
Published Print	33 years, 5 months ago (March 15, 1992)

Funders 0

None

BibTeX

@article{Rinnen_1992, title={Direct infrared and visible absorption spectroscopy of stoichiometric and nonstoichiometric clusters of indium phosphide}, volume={96}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.461864}, DOI={10.1063/1.461864}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Rinnen, K.-D. and Kolenbrander, K. D. and DeSantolo, A. M. and Mandich, M. L.}, year={1992}, month=mar, pages={4088–4101} }

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