DOI: 10.1063/1.461788. The influence of wave vector dependent dielectric properties on rotational friction. Rotational diffusion of phenoxazine dyes

The influence of wave vector dependent dielectric properties on rotational friction. Rotational diffusion of phenoxazine dyes

10.1063/1.461788

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The rotational diffusion of three mechanically similar phenoxazine dyes possessing distinct electrical properties was studied in isopropanol. The results, along with previously presented results from other polar solvents, were analyzed in terms of continuum theories for rotational dielectric friction. It was found that a continuum based theory can account for the observed rotational relaxation dynamics, but only with realistic modeling of the solute charge distribution (not a point dipole), and by accounting for both frequency and wave vector dependences of the solvent dielectric properties.

Bibliography

Alavi, D. S., Hartman, R. S., & Waldeck, D. H. (1991). The influence of wave vector dependent dielectric properties on rotational friction. Rotational diffusion of phenoxazine dyes. The Journal of Chemical Physics, 95(9), 6770â6783.

Authors 3

D. S. Alavi (first)
R. S. Hartman (additional)
D. H. Waldeck (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:21 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 8:31 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 12:21 a.m.)
Issued	33 years, 10 months ago (Nov. 1, 1991)
Published	33 years, 10 months ago (Nov. 1, 1991)
Published Print	33 years, 10 months ago (Nov. 1, 1991)

Funders 0

None

BibTeX

@article{Alavi_1991, title={The influence of wave vector dependent dielectric properties on rotational friction. Rotational diffusion of phenoxazine dyes}, volume={95}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.461788}, DOI={10.1063/1.461788}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Alavi, D. S. and Hartman, R. S. and Waldeck, D. H.}, year={1991}, month=nov, pages={6770–6783} }

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