DOI: 10.1063/1.461560. Resonant third-harmonic generation in all-trans β-carotene: The vibronic origins of the third-order nonlinear susceptibility in the visible region

Resonant third-harmonic generation in all-trans β-carotene: The vibronic origins of the third-order nonlinear susceptibility in the visible region

10.1063/1.461560

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The dispersion of the modulus of the third-order nonlinear susceptibility, ‖χ(3)zzzz(−3ω;ω,ω,ω)‖, of an all-trans β-carotene doped polystyrene thin film has been measured by third-harmonic generation throughout the 1 1Bu absorption band of the β-carotene. The observed dispersion is interpreted in terms of a three-electronic state model including explicit regard to six Franck–Condon active normal modes in the resonant electronic state. Both the sum-over-states method and, equivalently, the time domain approach are used. A fit of the three-state model to the data shows that the large nonlinear susceptibility of β-carotene in this wavelength range can be explained by strong dipole coupling between the strong one-photon allowed 1 1Bu state and a nearby two-photon allowed n 1Ag state. The electric dipole transition moment between the 1 1Bu excited state and the n 1Ag excited state, located at 22 200 cm−1, was determined to be 31 D.

Bibliography

van Beek, J. B., Kajzar, F., & Albrecht, A. C. (1991). Resonant third-harmonic generation in all-trans Î²-carotene: The vibronic origins of the third-order nonlinear susceptibility in the visible region. The Journal of Chemical Physics, 95(9), 6400â6412.

Authors 3

J. B. van Beek (first)
F. Kajzar (additional)
A. C. Albrecht (additional)

References 51 Referenced 61

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Dates

Type	When
Created	23 years ago (July 26, 2002, 8:21 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 8:38 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 2:33 a.m.)
Issued	33 years, 9 months ago (Nov. 1, 1991)
Published	33 years, 9 months ago (Nov. 1, 1991)
Published Print	33 years, 9 months ago (Nov. 1, 1991)

Funders 0

None

BibTeX

@article{van_Beek_1991, title={Resonant third-harmonic generation in all-trans β-carotene: The vibronic origins of the third-order nonlinear susceptibility in the visible region}, volume={95}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.461560}, DOI={10.1063/1.461560}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={van Beek, J. B. and Kajzar, F. and Albrecht, A. C.}, year={1991}, month=nov, pages={6400–6412} }

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