DOI: 10.1063/1.461061. Rydberg series of charge-transfer excitations: Cl and H in rare gas crystals

Rydberg series of charge-transfer excitations: Cl and H in rare gas crystals

10.1063/1.461061

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Rydberg series observed in the excitation spectra of Cl and H atoms isolated in the rare gas (Rg) crystals Kr and Xe are associated with the charge transfer species Cl−Rg+ and H−Rg+. The progressions originate from hole states of Rg+ which converge to the top of the rare gas valence band in an analogous manner to the convergence of conventional exciton states to the bottom of the conduction band. A model based on the effective mass approximation and a quantum defect concept predicted such progressions in Xe and Kr crystals and it is supported by the present results.

Bibliography

Kunz, H., McCaffrey, J. G., Chergui, M., Schriever, R., Ãnal, Ã., Stepanenko, V., & Schwentner, N. (1991). Rydberg series of charge-transfer excitations: Cl and H in rare gas crystals. The Journal of Chemical Physics, 95(3), 1466â1472.

Authors 7

H. Kunz (first)
J. G. McCaffrey (additional)
M. Chergui (additional)
R. Schriever (additional)
Ö. Ünal (additional)
V. Stepanenko (additional)
N. Schwentner (additional)

References 32 Referenced 26

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{'key': '2024021011261765100_r6'}
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{'key': '2024021011261765100_r10'}
{'key': '2024021011261765100_r11'}
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:59 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 8:11 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 5:40 a.m.)
Issued	34 years, 1 month ago (Aug. 1, 1991)
Published	34 years, 1 month ago (Aug. 1, 1991)
Published Print	34 years, 1 month ago (Aug. 1, 1991)

Funders 0

None

BibTeX

@article{Kunz_1991, title={Rydberg series of charge-transfer excitations: Cl and H in rare gas crystals}, volume={95}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.461061}, DOI={10.1063/1.461061}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kunz, H. and McCaffrey, J. G. and Chergui, M. and Schriever, R. and Ünal, Ö. and Stepanenko, V. and Schwentner, N.}, year={1991}, month=aug, pages={1466–1472} }

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