DOI: 10.1063/1.460387. Electronic relaxation of Xe2Cl in gaseous and supercritical fluid xenon

Electronic relaxation of Xe2Cl in gaseous and supercritical fluid xenon

10.1063/1.460387

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Spectroscopic and kinetic studies of the triatomic Xe2Cl exciplex in gaseous and supercritical fluid xenon up to 150 atm are reported. Clustering of the exciplex with Xe atoms is observed and its effect on spectral shifts, radiative lifetimes, and collisional deactivation are discussed. A kinetic treatment, incorporating diffusion controlled encounter probabilities, is used for the analysis of the relaxation data throughout the studied range. The radiative lifetime of the exciplex is observed to be 328(±20) ns, the exciplex is quenched by molecular chlorine with a rate constant of 7(±1)×10−10 cm3 s−1, while quenching by Xe is imperceptible even at the highest densities, implying a rate constant ≤10−17 cm3 s−1. Observations of transient loss, and their implications with respect to condensed phase triatomic rare gas halide exciplex lasers, are discussed.

Bibliography

Okada, F., & Apkarian, V. A. (1991). Electronic relaxation of Xe2Cl in gaseous and supercritical fluid xenon. The Journal of Chemical Physics, 94(1), 133â144.

Authors 2

F. Okada (first)
V. A. Apkarian (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:34 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 7:33 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 8:11 a.m.)
Issued	34 years, 8 months ago (Jan. 1, 1991)
Published	34 years, 8 months ago (Jan. 1, 1991)
Published Print	34 years, 8 months ago (Jan. 1, 1991)

Funders 0

None

BibTeX

@article{Okada_1991, title={Electronic relaxation of Xe2Cl in gaseous and supercritical fluid xenon}, volume={94}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.460387}, DOI={10.1063/1.460387}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Okada, F. and Apkarian, V. A.}, year={1991}, month=jan, pages={133–144} }

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