DOI: 10.1063/1.460177. Liquid crystalline properties of solutions of persistent polymer chains

Liquid crystalline properties of solutions of persistent polymer chains

10.1063/1.460177

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A synthesis of theories for the orientational entropy and excluded volume interaction for persistent chain polymers at intermediate degrees of chain flexibility, when extended to liquidlike densities, is shown to satisfactorily account for experimental data on the volume fractions of polymer at coexistence of isotropic and anisotropic phases, the concentration dependence of the order parameter within the lyotropic liquid crystal and the osmotic pressure equation of state for several extended chain polymers. Results of this continuum model are also compared with the virial approximation and treatments of the macromolecule as a rigid rod.

Bibliography

DuPrÃ©, D. B., & Yang, S. (1991). Liquid crystalline properties of solutions of persistent polymer chains. The Journal of Chemical Physics, 94(11), 7466â7477.

Authors 2

Donald B. DuPré (first)
Shi-jun Yang (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 8:20 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 7:55 a.m.)
Indexed	3 months, 2 weeks ago (May 6, 2025, 12:45 a.m.)
Issued	34 years, 2 months ago (June 1, 1991)
Published	34 years, 2 months ago (June 1, 1991)
Published Print	34 years, 2 months ago (June 1, 1991)

Funders 0

None

BibTeX

@article{DuPr__1991, title={Liquid crystalline properties of solutions of persistent polymer chains}, volume={94}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.460177}, DOI={10.1063/1.460177}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={DuPré, Donald B. and Yang, Shi-jun}, year={1991}, month=jun, pages={7466–7477} }

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