Solvent mobility in polystyrene/Aroclor solutions by depolarized Rayleigh scattering
10.1063/1.459670
Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

We report evidence of modification of solvent reorientation induced by the presence of polymer in polymer/solvent systems. Depolarized Rayleigh spectroscopy (DRS) has been used to probe the rotational motion of neat Aroclor and polystyrene (PS) solutions with polymer concentration 0.05, 0.086, and 0.146 g/cm3. The depolarized (IVH(ω)) spectra were recorded in the temperature range 40 to 140 °C using Fabry-Perot interferometry. Two Lorentzian lines were found to fit well the experimental IVH(ω) of PS/Aroclor above 60 °C revealing two populations of solvent. The fast relaxation time τf is virtually insensitive to variations of PS content in contrast to a considerable slowing down effect on the slow reorientation time τs obtained more precisely from photon correlation and oscillatory electric birefrigence measurements at low temperatures (<0 °C). The intensity Is of the narrow Lorentzian component, which was found to increase rapidly below a characteristic temperature at given PS concentration, is associated with the slow orientation of the solvent in the PS environment. Surprisingly, the onset of PS induced modification occurs at rather high temperatures (∼Tg+110 K). The values of the intensity ratio Is/If are rationalized in the framework of the restricted rotational diffusion model. Alternatively, the study of the single Lorentzian IVH(ω) spectra of the neat solvent suggests a significant amount of orientational pair correlations and is consistent with clustering in liquid Aroclor.

Bibliography

Fytas, G., Rizos, A., Floudas, G., & Lodge, T. P. (1990). Solvent mobility in polystyrene/Aroclor solutions by depolarized Rayleigh scattering. The Journal of Chemical Physics, 93(7), 5096–5104.

Authors 4
  1. G. Fytas (first)
  2. A. Rizos (additional)
  3. G. Floudas (additional)
  4. T. P. Lodge (additional)
References 44 Referenced 36
  1. 10.1021/ma00133a017 / Macromolecules (1984)
  2. 10.1021/ma60078a059 / Macromolecules (1980)
  3. {'key': '2024021010134104000_r3'}
  4. {'key': '2024021010134104000_r4'}
  5. {'key': '2024021010134104000_r5'}
  6. 10.1063/1.455372 / J. Chem. Phys. (1988)
  7. 10.1021/ma00191a054 / Macromolecules (1989)
  8. 10.1063/1.439024 / J. Chem. Phys. (1980)
  9. {'key': '2024021010134104000_r9', 'first-page': '2155', 'volume': '13', 'year': '1987', 'journal-title': 'J. Polym. Sci. Polym. Phys. Ed.'} / J. Polym. Sci. Polym. Phys. Ed. (1987)
  10. 10.1016/0032-3861(75)90188-3 / Polymer (1975)
  11. 10.1021/ma60077a027 / Macromolecules (1980)
  12. 10.1016/0032-3861(85)90031-X / Polym. (1985)
  13. {'key': '2024021010134104000_r13'}
  14. {'key': '2024021010134104000_r14', 'first-page': '3374', 'volume': '80', 'year': '1984', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1984)
  15. {'key': '2024021010134104000_r15'}
  16. 10.1021/ma00153a025 / Macromolecules (1985)
  17. 10.1021/ma00206a032 / Macromolecules (1990)
  18. 10.1063/1.442626 / J. Chem. Phys. (1981)
  19. 10.1063/1.444605 / J. Chem. Phys. (1983)
  20. 10.1021/ma60066a034 / Macromolecules (1978)
  21. {'key': '2024021010134104000_r21'}
  22. 10.1002/pol.1979.180170907 / J. Polym. Sci. Polym. Phys. Ed. (1979)
  23. {'key': '2024021010134104000_r23'}
  24. 10.1063/1.456632 / J. Chem. Phys. (1989)
  25. 10.1063/1.437759 / J. Chem. Phys. (1979)
  26. 10.1063/1.457197 / J. Chem. Phys. (1989)
  27. {'key': '2024021010134104000_r27', 'first-page': '6840', 'volume': '96', 'year': '1984', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. (1984)
  28. 10.1063/1.430883 / J. Chem. Phys. (1975)
  29. 10.1063/1.443564 / J. Chem. Phys. (1982)
  30. 10.1080/00268978800101211 / Mol. Phys. (1988)
  31. {'key': '2024021010134104000_r29'}
  32. {'key': '2024021010134104000_r30'}
  33. 10.1063/1.1680910 / J. Chem. Phys. (1974)
  34. 10.1021/ja00829a004 / J. Am. Chem. Soc. (1974)
  35. 10.1063/1.456264 / J. Chem. Phys. (1989)
  36. 10.1016/0009-2614(71)80510-9 / Chem. Phys. Lett. (1971)
  37. 10.1063/1.439654 / J. Chem. Phys. (1980)
  38. 10.1063/1.441987 / J. Chem. Phys. (1981)
  39. 10.1002/bbpc.19900940338 / Ber. Bunsenges. Phys. Chem. (1990)
  40. 10.1063/1.457830 / J. Chem. Phys. (1990)
  41. {'key': '2024021010134104000_r38'}
  42. 10.1039/F29848000283 / J. Chem. Soc. Faraday Trans. (1984)
  43. 10.1063/1.455085 / J. Chem. Phys. (1988)
  44. 10.1080/00268977800101631 / Mol. Phys. (1978)
Dates
Type When
Created 23 years ago (July 26, 2002, 9:21 a.m.)
Deposited 1 year, 6 months ago (Feb. 10, 2024, 7:04 a.m.)
Indexed 1 year, 5 months ago (March 20, 2024, 10:01 p.m.)
Issued 34 years, 10 months ago (Oct. 1, 1990)
Published 34 years, 10 months ago (Oct. 1, 1990)
Published Print 34 years, 10 months ago (Oct. 1, 1990)
Funders 0

None

@article{Fytas_1990, title={Solvent mobility in polystyrene/Aroclor solutions by depolarized Rayleigh scattering}, volume={93}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.459670}, DOI={10.1063/1.459670}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Fytas, G. and Rizos, A. and Floudas, G. and Lodge, T. P.}, year={1990}, month=oct, pages={5096–5104} }