DOI: 10.1063/1.458823. Microscopic dynamics of flow in molecularly narrow pores

Microscopic dynamics of flow in molecularly narrow pores

10.1063/1.458823

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Flow of fluids confined in molecularly narrow pores is studied by molecular dynamics. Strong density variations across the pore render the usual dependence of the local viscosity on local density inappropriate. At separations greater than four molecular diameters flow can be described by a simple redefinition of local viscosity. In narrower pores a dramatic increase of effective viscosities is observed and is due to the inability of fluid layers to undergo the gliding motion of planar flow. This effect is partially responsible for the strong viscosity increases observed experimentally in thin films that still maintain their fluidity.

Bibliography

Bitsanis, I., Somers, S. A., Davis, H. T., & Tirrell, M. (1990). Microscopic dynamics of flow in molecularly narrow pores. The Journal of Chemical Physics, 93(5), 3427â3431.

Authors 4

Ioannis Bitsanis (first)
Susan A. Somers (additional)
H. Ted Davis (additional)
Matthew Tirrell (additional)

References 18 Referenced 120

10.1146/annurev.pc.34.100183.000535 / Annu. Rev. Phys. Chem. (1983)
10.1038/329427a0 / Nature (1987)
10.1038/329390a0 / Nature (1987)
10.1103/PhysRevLett.60.1282 / Phys. Rev. Lett. (1988)
10.1103/PhysRevA.40.1144 / Phys. Rev. A (1989)
10.1071/CH9802139 / Aust. J. Chem. (1980)
{'key': '2024021010103926400_r6', 'first-page': '2836', 'volume': '22', 'year': '1980', 'journal-title': 'Pys. Rev. A'} / Pys. Rev. A (1980)
10.1103/PhysRevA.31.2672 / Phys. Rev. A (1985)
10.1063/1.1747782 / J. Chem. Phys. (1950)
10.1063/1.453240 / J. Chem. Phys. (1987)
10.1063/1.439489 / J. Chem. Phys. (1980)
10.1103/PhysRevA.11.658 / Phys. Rev. A (1975)
10.1063/1.454972 / J. Chem. Phys. (1988)
10.1063/1.454211 / J. Chem. Phys. (1988)
10.1063/1.449693 / J. Chem. Phys. (1985)
10.1126/science.241.4867.795 / Science (1988)
10.1103/PhysRevLett.61.2570 / Phys. Rev. Lett. (1988)
10.1126/science.245.4923.1223 / Science (1989)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:12 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 7 a.m.)
Indexed	2 months, 1 week ago (June 21, 2025, 5:02 a.m.)
Issued	34 years, 11 months ago (Sept. 1, 1990)
Published	34 years, 11 months ago (Sept. 1, 1990)
Published Print	34 years, 11 months ago (Sept. 1, 1990)

Funders 0

None

BibTeX

@article{Bitsanis_1990, title={Microscopic dynamics of flow in molecularly narrow pores}, volume={93}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.458823}, DOI={10.1063/1.458823}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Bitsanis, Ioannis and Somers, Susan A. and Davis, H. Ted and Tirrell, Matthew}, year={1990}, month=sep, pages={3427–3431} }

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