DOI: 10.1063/1.458166. Rotational dynamics of anthracene and 9,10-dimethylanthracene in polyisoprene

Rotational dynamics of anthracene and 9,10-dimethylanthracene in polyisoprene

10.1063/1.458166

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Singlet and triplet transient grating experiments have been used to measure rotational correlation functions for anthracene and 9,10-dimethylanthracene in cis-polyisoprene from Tg+120 °C to Tg+20 °C. Over this temperature range, the rotational correlation time varies by seven decades and follows the temperature dependence of the bulk viscosity. The observed correlation functions are not consistent with predictions of the anisotropic rotational diffusion model. The observed correlation functions for anthracene are consistent with a change in the predominant axis for rotational diffusion as a function of temperature. At high temperatures, in-plane rotation occurs most rapidly, while at low temperatures rotation about the long axis predominates.

Bibliography

Hyde, P. D., & Ediger, M. D. (1990). Rotational dynamics of anthracene and 9,10-dimethylanthracene in polyisoprene. The Journal of Chemical Physics, 92(2), 1036â1044.

Authors 2

Patrick D. Hyde (first)
M. D. Ediger (additional)

References 47 Referenced 47

10.1021/j150618a009 / J. Phys. Chem. (1981)
10.1016/0009-2614(83)87495-8 / Chem. Phys. Lett. (1983)
10.1063/1.453373 / J. Chem. Phys. (1987)
10.1063/1.452928 / J. Chem. Phys. (1987)
10.1021/j100271a030 / J. Phys. Chem. (1985)
10.1063/1.434482 / J. Chem. Phys. (1977)
10.1016/0301-0104(77)85035-0 / Chem. Phys. (1977)
10.1016/0009-2614(73)89006-2 / Chem. Phys. Lett. (1973)
10.1021/j100280a100 / J. Phys. Chem. (1986)
10.1021/ma00184a032 / Macromolecules (1988)
10.1039/fs9720600014 / J. Chem. Soc., Faraday Symp. (1972)
10.1080/00222357908080913 / J. Macromol. Sci. Rev. Macromol. Chem. C (1979)
10.1021/ma00195a044 / Macromolecules (1989)
10.1063/1.446802 / J. Chem. Phys. (1984)
10.1021/j100221a011 / J. Phys. Chem. (1982)
10.1103/PhysRevB.25.2645 / Phys. Rev. B (1982)
10.1063/1.329864 / J. Appl. Phys. (1982)
10.1021/ma00164a013 / Macromolecules (1986)
10.1021/ma00193a056 / Macromolecules (1989)
10.1080/713819604 / Opt. Acta (1977)
10.1007/BF00619824 / Opt. Quantum Electron. (1979)
{'key': '2024021009184663800_r22'}
{'key': '2024021009184663800_r23'}
10.1063/1.1678194 / J. Chem. Phys. (1972)
10.1063/1.1725245 / J. Chem. Phys. (1964)
10.1063/1.1726941 / J. Chem. Phys. (1966)
{'key': '2024021009184663800_r27'}
10.1016/0301-0104(74)80061-3 / Chem. Phys. (1974)
10.1016/0009-2614(69)80049-7 / Chem. Phys. Lett. (1969)
10.1021/ma00193a093 / Macromolecules (1989)
{'key': '2024021009184663800_r31'}
10.1021/ma60020a016 / Macromolecules (1971)
{'key': '2024021009184663800_r32a'}
{'key': '2024021009184663800_r33'}
{'key': '2024021009184663800_r34'}
10.1016/0032-3861(86)90011-X / Polymer (1986)
{'key': '2024021009184663800_r36'}
{'key': '2024021009184663800_r36a'}
10.1063/1.1659835 / J. Appl. Phys. (1971)
10.1021/ma00145a028 / Macromolecules (1985)
{'key': '2024021009184663800_r38', 'first-page': '1083', 'volume': '88', 'year': '1989', 'journal-title': 'J. Chem. Soc., Faraday Soc. I'} / J. Chem. Soc., Faraday Soc. I (1989)
10.1021/ma60071a028 / Macromolecules (1979)
{'key': '2024021009184663800_r40'}
10.1063/1.442468 / J. Chem. Phys. (1981)
{'key': '2024021009184663800_r41'}
{'key': '2024021009184663800_r42'}
10.1021/bi00630a002 / Biochemistry (1977)

Dates

Type	When
Created	23 years ago (July 26, 2002, 9:12 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 6:02 a.m.)
Indexed	1 year, 5 months ago (March 22, 2024, 6:23 a.m.)
Issued	35 years, 7 months ago (Jan. 15, 1990)
Published	35 years, 7 months ago (Jan. 15, 1990)
Published Print	35 years, 7 months ago (Jan. 15, 1990)

Funders 0

None

BibTeX

@article{Hyde_1990, title={Rotational dynamics of anthracene and 9,10-dimethylanthracene in polyisoprene}, volume={92}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.458166}, DOI={10.1063/1.458166}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hyde, Patrick D. and Ediger, M. D.}, year={1990}, month=jan, pages={1036–1044} }

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