DOI: 10.1063/1.457617. Theory of transient hole-burning spectrum for molecules in solution

Theory of transient hole-burning spectrum for molecules in solution

10.1063/1.457617

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Theory based on a configuration coordinate model is presented to clarify solute–solvent relaxation effect on the line shape of a time-resolved hole-burning spectrum. The time-resolved hole-burning spectrum is affected by both a hole created in a ground-state population and an excess excited-state population. The solute–solvent relaxation causes thermalization in both populations and then the shift and broadening of the spectrum is expected observable. The line shapes of three typical cases are mainly considered: (1) The excited state is assumed to have an infinitely long lifetime; (2) the excited state has a finite lifetime, the population being assumed to relax toward an electronic state other than the ground state, and (3) the population created in the excited state relaxes to the ground state, where a hole-filling effect is taken into account. Results obtained by numerical calculations show that a time evolution of the ground-state hole is clearly observed when the low-energy tail of the absorption band is excited under the condition that the population decay to the other electronic state is very fast. Further, it is predicted that the hole-filling effect causes a considerable deformation of the spectral shape when the solvent relaxation rate is comparable to the excited-state population decay rate.

Bibliography

Kinoshita, S. (1989). Theory of transient hole-burning spectrum for molecules in solution. The Journal of Chemical Physics, 91(9), 5175â5184.

Authors 1

Shuichi Kinoshita (first)

References 37 Referenced 57

10.1063/1.455383 / J. Chem. Phys. (1988)
10.1016/0009-2614(88)85039-5 / Chem. Phys. Lett. (1988)
10.1021/j100323a068 / J. Phys. Chem. (1988)
10.1021/j100336a002 / J. Phys. Chem. (1988)
10.1063/1.456520 / J. Chem. Phys. (1989)
10.1016/0009-2614(89)87479-2 / Chem. Phys. Lett. (1989)
10.1016/0009-2614(85)85120-4 / Chem. Phys. Lett. (1985)
10.1016/0009-2614(86)80622-4 / Chem. Phys. Lett. (1986)
10.1016/0009-2614(88)85227-8 / Chem. Phys. Lett. (1988)
{'key': '2024021008560541200_r6'}
10.1143/JPSJ.56.4162 / J. Phys. Soc. Jpn. (1987)
10.1016/0009-2614(87)87202-0 / Chem. Phys. Lett. (1987)
10.1016/0022-2313(88)90330-4 / J. Lumin. (1988)
{'key': '2024021008560541200_r9', 'first-page': '419', 'volume': 'C7', 'year': '1985', 'journal-title': 'J. Phys. (Paris)'} / J. Phys. (Paris) (1985)
10.1016/S0009-2614(86)80038-0 / Chem. Phys. Lett. (1986)
10.1063/1.452860 / J. Chem. Phys. (1987)
{'key': '2024021008560541200_r9c'}
10.1016/0009-2614(87)87210-X / Chem. Phys. Lett. (1987)
10.1063/1.453507 / J. Chem. Phys. (1987)
10.1109/3.122 / IEEE J. Quantum Electron. (1988)
{'key': '2024021008560541200_r12'}
{'key': '2024021008560541200_r13', 'first-page': '490', 'volume': '28', 'year': '1970', 'journal-title': 'Opt. Spectrosc.'} / Opt. Spectrosc. (1970)
10.1016/0009-2614(83)87496-X / Chem. Phys. Lett. (1983)
10.1063/1.445091 / J. Chem. Phys. (1983)
10.1016/0301-0104(84)80014-2 / Chem. Phys. (1984)
10.1063/1.450804 / J. Chem. Phys. (1986)
10.1063/1.454923 / J. Chem. Phys. (1988)
10.1016/0009-2614(88)80067-8 / Chem. Phys. Lett. (1988)
{'key': '2024021008560541200_r13g', 'first-page': '533', 'volume': '155', 'year': '1988', 'journal-title': 'Chem. Phys. Lett.'} / Chem. Phys. Lett. (1988)
10.1016/0009-2614(87)80019-2 / Chem. Phys. Lett. (1987)
10.1063/1.454193 / J. Chem. Phys. (1988)
10.1063/1.451625 / J. Chem. Phys. (1986)
{'key': '2024021008560541200_r16'}
10.1016/0009-2614(88)87379-2 / Chem. Phys. Lett. (1988)
10.1063/1.452632 / J. Chem. Phys. (1987)
10.1063/1.453920 / J. Chem. Phys. (1988)
10.1063/1.454811 / J. Chem. Phys. (1988)

Dates

Type	When
Created	23 years ago (July 26, 2002, 9:21 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 5:43 a.m.)
Indexed	1 year, 2 months ago (June 19, 2024, 6:37 a.m.)
Issued	35 years, 9 months ago (Nov. 1, 1989)
Published	35 years, 9 months ago (Nov. 1, 1989)
Published Print	35 years, 9 months ago (Nov. 1, 1989)

Funders 0

None

BibTeX

@article{Kinoshita_1989, title={Theory of transient hole-burning spectrum for molecules in solution}, volume={91}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.457617}, DOI={10.1063/1.457617}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Kinoshita, Shuichi}, year={1989}, month=nov, pages={5175–5184} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        6,
        19
      ]
    ],
    "date-time": "2024-06-19T10:37:45Z",
    "timestamp": 1718793465395
  },
  "reference-count": 37,
  "publisher": "AIP Publishing",
  "issue": "9",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1989,
        11,
        1
      ]
    ]
  },
  "abstract": "<jats:p>Theory based on a configuration coordinate model is presented to clarify solute\u2013solvent relaxation effect on the line shape of a time-resolved hole-burning spectrum. The time-resolved hole-burning spectrum is affected by both a hole created in a ground-state population and an excess excited-state population. The solute\u2013solvent relaxation causes thermalization in both populations and then the shift and broadening of the spectrum is expected observable. The line shapes of three typical cases are mainly considered: (1) The excited state is assumed to have an infinitely long lifetime; (2) the excited state has a finite lifetime, the population being assumed to relax toward an electronic state other than the ground state, and (3) the population created in the excited state relaxes to the ground state, where a hole-filling effect is taken into account. Results obtained by numerical calculations show that a time evolution of the ground-state hole is clearly observed when the low-energy tail of the absorption band is excited under the condition that the population decay to the other electronic state is very fast. Further, it is predicted that the hole-filling effect causes a considerable deformation of the spectral shape when the solvent relaxation rate is comparable to the excited-state population decay rate.</jats:p>",
  "DOI": "10.1063/1.457617",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T13:21:59Z",
    "timestamp": 1027689719000
  },
  "page": "5175-5184",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 57,
  "title": "Theory of transient hole-burning spectrum for molecules in solution",
  "prefix": "10.1063",
  "volume": "91",
  "author": [
    {
      "given": "Shuichi",
      "family": "Kinoshita",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Physics, Osaka University, Toyonaka, Osaka 560, Japan"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024021008560541200_r1",
      "doi-asserted-by": "crossref",
      "first-page": "6612",
      "DOI": "10.1063/1.455383",
      "volume": "89",
      "year": "1988",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r2",
      "doi-asserted-by": "crossref",
      "first-page": "1",
      "DOI": "10.1016/0009-2614(88)85039-5",
      "volume": "146",
      "year": "1988",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r2a",
      "doi-asserted-by": "crossref",
      "first-page": "3679",
      "DOI": "10.1021/j100323a068",
      "volume": "92",
      "year": "1988",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021008560541200_r2b",
      "doi-asserted-by": "crossref",
      "first-page": "7039",
      "DOI": "10.1021/j100336a002",
      "volume": "92",
      "year": "1988",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021008560541200_r2c",
      "doi-asserted-by": "crossref",
      "first-page": "151",
      "DOI": "10.1063/1.456520",
      "volume": "90",
      "year": "1989",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r2d",
      "doi-asserted-by": "crossref",
      "first-page": "593",
      "DOI": "10.1016/0009-2614(89)87479-2",
      "volume": "155",
      "year": "1989",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r3",
      "doi-asserted-by": "crossref",
      "first-page": "456",
      "DOI": "10.1016/0009-2614(85)85120-4",
      "volume": "114",
      "year": "1985",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r4",
      "doi-asserted-by": "crossref",
      "first-page": "341",
      "DOI": "10.1016/0009-2614(86)80622-4",
      "volume": "132",
      "year": "1986",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r5",
      "doi-asserted-by": "crossref",
      "first-page": "376",
      "DOI": "10.1016/0009-2614(88)85227-8",
      "volume": "153",
      "year": "1988",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r6"
    },
    {
      "key": "2024021008560541200_r7",
      "doi-asserted-by": "crossref",
      "first-page": "4162",
      "DOI": "10.1143/JPSJ.56.4162",
      "volume": "56",
      "year": "1987",
      "journal-title": "J. Phys. Soc. Jpn."
    },
    {
      "key": "2024021008560541200_r8",
      "doi-asserted-by": "crossref",
      "first-page": "605",
      "DOI": "10.1016/0009-2614(87)87202-0",
      "volume": "134",
      "year": "1987",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r8a",
      "doi-asserted-by": "crossref",
      "first-page": "561",
      "DOI": "10.1016/0022-2313(88)90330-4",
      "volume": "40/41",
      "year": "1988",
      "journal-title": "J. Lumin."
    },
    {
      "key": "2024021008560541200_r9",
      "first-page": "419",
      "volume": "C7",
      "year": "1985",
      "journal-title": "J. Phys. (Paris)"
    },
    {
      "key": "2024021008560541200_r9a",
      "doi-asserted-by": "crossref",
      "first-page": "197",
      "DOI": "10.1016/S0009-2614(86)80038-0",
      "volume": "126",
      "year": "1986",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r9b",
      "doi-asserted-by": "crossref",
      "first-page": "4471",
      "DOI": "10.1063/1.452860",
      "volume": "87",
      "year": "1987",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r9c"
    },
    {
      "key": "2024021008560541200_r10",
      "doi-asserted-by": "crossref",
      "first-page": "23",
      "DOI": "10.1016/0009-2614(87)87210-X",
      "volume": "135",
      "year": "1987",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r10a",
      "doi-asserted-by": "crossref",
      "first-page": "5840",
      "DOI": "10.1063/1.453507",
      "volume": "87",
      "year": "1987",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r11",
      "doi-asserted-by": "crossref",
      "first-page": "261",
      "DOI": "10.1109/3.122",
      "volume": "24",
      "year": "1988",
      "journal-title": "IEEE J. Quantum Electron."
    },
    {
      "key": "2024021008560541200_r12"
    },
    {
      "key": "2024021008560541200_r13",
      "first-page": "490",
      "volume": "28",
      "year": "1970",
      "journal-title": "Opt. Spectrosc."
    },
    {
      "key": "2024021008560541200_r13a",
      "doi-asserted-by": "crossref",
      "first-page": "367",
      "DOI": "10.1016/0009-2614(83)87496-X",
      "volume": "101",
      "year": "1983",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r13b",
      "doi-asserted-by": "crossref",
      "first-page": "4145",
      "DOI": "10.1063/1.445091",
      "volume": "78",
      "year": "1983",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r13c",
      "doi-asserted-by": "crossref",
      "first-page": "257",
      "DOI": "10.1016/0301-0104(84)80014-2",
      "volume": "86",
      "year": "1984",
      "journal-title": "Chem. Phys."
    },
    {
      "key": "2024021008560541200_r13d",
      "doi-asserted-by": "crossref",
      "first-page": "4272",
      "DOI": "10.1063/1.450804",
      "volume": "84",
      "year": "1986",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r13e",
      "doi-asserted-by": "crossref",
      "first-page": "3519",
      "DOI": "10.1063/1.454923",
      "volume": "89",
      "year": "1988",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r13f",
      "doi-asserted-by": "crossref",
      "first-page": "47",
      "DOI": "10.1016/0009-2614(88)80067-8",
      "volume": "151",
      "year": "1988",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r13g",
      "first-page": "533",
      "volume": "155",
      "year": "1988",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r14",
      "doi-asserted-by": "crossref",
      "first-page": "87",
      "DOI": "10.1016/0009-2614(87)80019-2",
      "volume": "134",
      "year": "1987",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r14a",
      "doi-asserted-by": "crossref",
      "first-page": "651",
      "DOI": "10.1063/1.454193",
      "volume": "88",
      "year": "1988",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r15",
      "doi-asserted-by": "crossref",
      "first-page": "462",
      "DOI": "10.1063/1.451625",
      "volume": "85",
      "year": "1986",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r16"
    },
    {
      "key": "2024021008560541200_r17",
      "doi-asserted-by": "crossref",
      "first-page": "270",
      "DOI": "10.1016/0009-2614(88)87379-2",
      "volume": "143",
      "year": "1988",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021008560541200_r18",
      "doi-asserted-by": "crossref",
      "first-page": "5133",
      "DOI": "10.1063/1.452632",
      "volume": "86",
      "year": "1987",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r18a",
      "doi-asserted-by": "crossref",
      "first-page": "3246",
      "DOI": "10.1063/1.453920",
      "volume": "88",
      "year": "1988",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021008560541200_r18b",
      "doi-asserted-by": "crossref",
      "first-page": "4288",
      "DOI": "10.1063/1.454811",
      "volume": "89",
      "year": "1988",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/91/9/5175/18982717/5175_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/91/9/5175/18982717/5175_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T10:43:06Z",
    "timestamp": 1707561786000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/91/9/5175/92822/Theory-of-transient-hole-burning-spectrum-for"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1989,
        11,
        1
      ]
    ]
  },
  "references-count": 37,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          1989,
          11,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.457617",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1989,
        11,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1989,
        11,
        1
      ]
    ]
  }
}