Abstract
The solvation dynamics of a pair of ions rigidly held a fixed distance from each other in either a dipolar hard-sphere solvent or a dipolar dumbbell solvent is investigated under the mean spherical approximation (MSA) applied to an interaction-site model in which the pair of ions is treated as a rigid extended dipolar dumbbell. An analytical expression for the reorganization free energy for a charge transfer reaction is obtained and compared with numerical results obtained via a thermodynamic cycle. Solvent effects on the rate of a charge transfer reaction are also investigated using the dielectric Green-function theory developed by Newton and Friedman.
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Dates
Type | When |
---|---|
Created | 23 years ago (July 26, 2002, 9:12 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 10, 2024, 5:55 a.m.) |
Indexed | 1 year, 6 months ago (Feb. 11, 2024, 8:03 a.m.) |
Issued | 35 years, 10 months ago (Oct. 15, 1989) |
Published | 35 years, 10 months ago (Oct. 15, 1989) |
Published Print | 35 years, 10 months ago (Oct. 15, 1989) |
@article{Zhou_1989, title={Analytical approach to molecular liquids. IV. Solvation dynamics and electron-transfer reactions}, volume={91}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.456727}, DOI={10.1063/1.456727}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Zhou, Yaoqi and Friedman, Harold L. and Stell, George}, year={1989}, month=oct, pages={4885–4890} }