Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

The solvation dynamics of a pair of ions rigidly held a fixed distance from each other in either a dipolar hard-sphere solvent or a dipolar dumbbell solvent is investigated under the mean spherical approximation (MSA) applied to an interaction-site model in which the pair of ions is treated as a rigid extended dipolar dumbbell. An analytical expression for the reorganization free energy for a charge transfer reaction is obtained and compared with numerical results obtained via a thermodynamic cycle. Solvent effects on the rate of a charge transfer reaction are also investigated using the dielectric Green-function theory developed by Newton and Friedman.

Bibliography

Zhou, Y., Friedman, H. L., & Stell, G. (1989). Analytical approach to molecular liquids. IV. Solvation dynamics and electron-transfer reactions. The Journal of Chemical Physics, 91(8), 4885–4890.

Authors 3
  1. Yaoqi Zhou (first)
  2. Harold L. Friedman (additional)
  3. George Stell (additional)
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Dates
Type When
Created 23 years ago (July 26, 2002, 9:12 a.m.)
Deposited 1 year, 6 months ago (Feb. 10, 2024, 5:55 a.m.)
Indexed 1 year, 6 months ago (Feb. 11, 2024, 8:03 a.m.)
Issued 35 years, 10 months ago (Oct. 15, 1989)
Published 35 years, 10 months ago (Oct. 15, 1989)
Published Print 35 years, 10 months ago (Oct. 15, 1989)
Funders 0

None

@article{Zhou_1989, title={Analytical approach to molecular liquids. IV. Solvation dynamics and electron-transfer reactions}, volume={91}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.456727}, DOI={10.1063/1.456727}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Zhou, Yaoqi and Friedman, Harold L. and Stell, George}, year={1989}, month=oct, pages={4885–4890} }