DOI: 10.1063/1.456612. The infrared spectra of nitrous oxide

The infrared spectra of nitrous oxide–HF isomers

10.1063/1.456612

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Two spectroscopically distinct isomers of a hydrogen bonded complex between nitrous oxide and hydrogen fluoride are observed by direct infrared laser absorption detection in a slit supersonic expansion. The linear isomer FH–NNO contains a relatively rigid hydrogen bond to the nitrogen end of NNO. The bent isomer NNO–HF has a stronger hydrogen bond to the oxygen end of NNO, but this bond is characterized by a softer bending potential and thus the complex exhibits evidence of large amplitude bending motion. Rapid vibrational predissociation, as determined from the homogeneous broadening of the rovibrational absorption structure, is evidenced in both isomers. The linear isomer exhibits predissociation lifetimes which show structure as a function of the upper J′ rotational level, including narrow resonances which suggest excitation of NNO fragment vibrational modes.

Bibliography

Lovejoy, C. M., & Nesbitt, D. J. (1989). The infrared spectra of nitrous oxideâHF isomers. The Journal of Chemical Physics, 90(9), 4671â4680.

Authors 2

Christopher M. Lovejoy (first)
David J. Nesbitt (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:10 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 4:29 a.m.)
Indexed	1 year, 1 month ago (Aug. 2, 2024, 4:32 a.m.)
Issued	36 years, 4 months ago (May 1, 1989)
Published	36 years, 4 months ago (May 1, 1989)
Published Print	36 years, 4 months ago (May 1, 1989)

Funders 0

None

BibTeX

@article{Lovejoy_1989, title={The infrared spectra of nitrous oxide–HF isomers}, volume={90}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.456612}, DOI={10.1063/1.456612}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Lovejoy, Christopher M. and Nesbitt, David J.}, year={1989}, month=may, pages={4671–4680} }

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