DOI: 10.1063/1.456572. Infrared fluorescence from NO2 excited at 400

Infrared fluorescence from NO2 excited at 400–500 nm

10.1063/1.456572

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

NO2 has been electronically excited to the 2B2/2B1 states, using pulsed dye laser radiation at 400–500 nm. Strong mixing of the electronically excited state with the ground electronic state (2A1) leads to highly vibrationally excited NO2(2A1), from which infrared emission has been observed. The time dependence of the IR fluorescence at several wavelengths has been observed, and quenching rate constants for NO2 and other gases have been measured. In addition to IR fluorescence at wavelengths identifiable as vibrational transitions (3.0–4.0, 6.1–6.8, 7.4–8.5, and 10.0–14.0 μm), emission at wavelengths &lt;3.0 μm has been observed and attributed to a transition with electronic character. The emission observed in these experiments has been compared with that of chemiluminescent NO2 produced in the O+NO and O3+NO reactions.

Bibliography

McAndrew, J. J. F., Preses, Jack. M., Weston, R. E., & Flynn, G. W. (1989). Infrared fluorescence from NO2 excited at 400â500 nm. The Journal of Chemical Physics, 90(9), 4772â4782.

Authors 4

James J. F. McAndrew (first)
Jack. M. Preses (additional)
Ralph E. Weston (additional)
George W. Flynn (additional)

References 30 Referenced 18

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:10 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 4:21 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 5:59 a.m.)
Issued	36 years, 3 months ago (May 1, 1989)
Published	36 years, 3 months ago (May 1, 1989)
Published Print	36 years, 3 months ago (May 1, 1989)

Funders 0

None

BibTeX

@article{McAndrew_1989, title={Infrared fluorescence from NO2 excited at 400–500 nm}, volume={90}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.456572}, DOI={10.1063/1.456572}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={McAndrew, James J. F. and Preses, Jack. M. and Weston, Ralph E. and Flynn, George W.}, year={1989}, month=may, pages={4772–4782} }

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