DOI: 10.1063/1.456290. On the structure and dynamics of lithium counterions in polyelectrolyte solutions: A nuclear magnetic resonance and neutron scattering study

On the structure and dynamics of lithium counterions in polyelectrolyte solutions: A nuclear magnetic resonance and neutron scattering study

10.1063/1.456290

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The structure around lithium counterions in polyacrylate solutions has been investigated by neutron diffraction, and it is concluded that small cations remain hydrated when they accumulate around a highly charged polymer. Interactions between the polyion and the counterions over a range outside the hydration shell are also observed. The relaxation rate of 7Li due to dipolar coupling to 17O was obtained by nuclear magnetic resonance. The results indicate that the polyion exerts a moderate influence on the reorientational dynamics of the lithium aqua-ion.

Bibliography

van der Maarel, J. R. C., Powell, D. H., Jawahier, A. K., Leyte-Zuiderweg, L. H., Neilson, G. W., & Bellissent-Funel, M. C. (1989). On the structure and dynamics of lithium counterions in polyelectrolyte solutions: A nuclear magnetic resonance and neutron scattering study. The Journal of Chemical Physics, 90(11), 6709â6715.

Authors 6

J. R. C. van der Maarel (first)
D. H. Powell (additional)
A. K. Jawahier (additional)
L. H. Leyte-Zuiderweg (additional)
G. W. Neilson (additional)
M. C. Bellissent-Funel (additional)

References 27 Referenced 31

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{'key': '2024021007332046900_r2'}
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10.1021/ma00176a011 / Macromolecules (1987)
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{'key': '2024021007332046900_r13'}
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{'key': '2024021007332046900_r18'}
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:20 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 4:28 a.m.)
Indexed	4 months, 1 week ago (April 30, 2025, 3:47 a.m.)
Issued	36 years, 3 months ago (June 1, 1989)
Published	36 years, 3 months ago (June 1, 1989)
Published Print	36 years, 3 months ago (June 1, 1989)

Funders 0

None

BibTeX

@article{van_der_Maarel_1989, title={On the structure and dynamics of lithium counterions in polyelectrolyte solutions: A nuclear magnetic resonance and neutron scattering study}, volume={90}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.456290}, DOI={10.1063/1.456290}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={van der Maarel, J. R. C. and Powell, D. H. and Jawahier, A. K. and Leyte-Zuiderweg, L. H. and Neilson, G. W. and Bellissent-Funel, M. C.}, year={1989}, month=jun, pages={6709–6715} }

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