DOI: 10.1063/1.455175. Vibration–rotation spectrum of the carbon dioxide–acetylene van der Waals complex in the 3 μ region

Vibration–rotation spectrum of the carbon dioxide–acetylene van der Waals complex in the 3 μ region

10.1063/1.455175

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The infrared absorption spectrum of the carbon dioxide–acetylene van der Waals complex has been observed in a pulsed molecular beam. A color center laser was used to excite the vibration associated with the antisymmetric hydrogen stretching mode of the acetylene monomer. The vibrational origin is 3281.740 cm−1 and the rotational constants are A″=8876, B″=2859, C″=2155, A′=8864, B′=2855, and C′=2154 MHz. The axes of the two monomer are parallel to one another and the complex has C2v symmetry. The separation of the monomer units is 3.285 Å. The angular part of the intermolecular potential function is discussed in terms of electrostatic interactions between distributed multipole moments.

Bibliography

Prichard, D. G., Nandi, R. N., Muenter, J. S., & Howard, B. J. (1988). Vibrationârotation spectrum of the carbon dioxideâacetylene van der Waals complex in the 3 Î¼ region. The Journal of Chemical Physics, 89(3), 1245â1250.

Authors 4

Diana G. Prichard (first)
R. N. Nandi (additional)
J. S. Muenter (additional)
B. J. Howard (additional)

References 24 Referenced 38

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10.1063/1.451059 / J. Chem. Phys. (1986)
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:12 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 3:22 a.m.)
Indexed	1 year ago (Aug. 29, 2024, 4:25 a.m.)
Issued	37 years, 1 month ago (Aug. 1, 1988)
Published	37 years, 1 month ago (Aug. 1, 1988)
Published Print	37 years, 1 month ago (Aug. 1, 1988)

Funders 0

None

BibTeX

@article{Prichard_1988, title={Vibration–rotation spectrum of the carbon dioxide–acetylene van der Waals complex in the 3 μ region}, volume={89}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.455175}, DOI={10.1063/1.455175}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Prichard, Diana G. and Nandi, R. N. and Muenter, J. S. and Howard, B. J.}, year={1988}, month=aug, pages={1245–1250} }

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