DOI: 10.1063/1.454861. Infrared line shapes of ethylidyne on the Pt(111) surface

Infrared line shapes of ethylidyne on the Pt(111) surface

10.1063/1.454861

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We have measured the temperature dependence of the infrared line shapes of three fundamental vibrations of the ethylidyne species, ≡C–CH3, on the Pt(111) surface. Each of the three line shapes possesses distinctly different properties. The C–C stretch shows the strongest temperature dependence. The full width at half-maximum (FWHM) varies quadratically with temperature from 6 cm−1 at 82 K to 10 cm−1 at 350 K. The frequency of the C–C stretch shows a linear shift from 1125 cm−1 at 82 K to 1117 cm−1 at 350 K. The symmetric C–H stretch shows a temperature independent frequency of 2883 cm−1 and only a small change in full width from 4.1 cm−1 at 82 K to 5.1 cm−1 at 300 K. The symmetric CH3 bend has an unusually narrow full width of 1.2 cm−1 at 82 K which increases to 2.4 cm−1 at 350 K while its frequency remains constant within the experimental error. The results are discussed in terms of current theories of vibrational line broadening for molecules adsorbed on metal surfaces.

Bibliography

Malik, I. J., Agrawal, V. K., & Trenary, M. (1988). Infrared line shapes of ethylidyne on the Pt(111) surface. The Journal of Chemical Physics, 89(6), 3861â3869.

Authors 3

Igor J. Malik (first)
Vijay K. Agrawal (additional)
Michael Trenary (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:12 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 3:30 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 8:41 a.m.)
Issued	36 years, 11 months ago (Sept. 15, 1988)
Published	36 years, 11 months ago (Sept. 15, 1988)
Published Print	36 years, 11 months ago (Sept. 15, 1988)

Funders 0

None

BibTeX

@article{Malik_1988, title={Infrared line shapes of ethylidyne on the Pt(111) surface}, volume={89}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.454861}, DOI={10.1063/1.454861}, number={6}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Malik, Igor J. and Agrawal, Vijay K. and Trenary, Michael}, year={1988}, month=sep, pages={3861–3869} }

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  "abstract": "<jats:p>We have measured the temperature dependence of the infrared line shapes of three fundamental vibrations of the ethylidyne species, \u2261C\u2013CH3, on the Pt(111) surface. Each of the three line shapes possesses distinctly different properties. The C\u2013C stretch shows the strongest temperature dependence. The full width at half-maximum (FWHM) varies quadratically with temperature from 6 cm\u22121 at 82 K to 10 cm\u22121 at 350 K. The frequency of the C\u2013C stretch shows a linear shift from 1125 cm\u22121 at 82 K to 1117 cm\u22121 at 350 K. The symmetric C\u2013H stretch shows a temperature independent frequency of 2883 cm\u22121 and only a small change in full width from 4.1 cm\u22121 at 82 K to 5.1 cm\u22121 at 300 K. The symmetric CH3 bend has an unusually narrow full width of 1.2 cm\u22121 at 82 K which increases to 2.4 cm\u22121 at 350 K while its frequency remains constant within the experimental error. The results are discussed in terms of current theories of vibrational line broadening for molecules adsorbed on metal surfaces.</jats:p>",
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