DOI: 10.1063/1.454791. Electronic and vibrational structure of transition metal trimers: Photoelectron spectra of Ni−3, Pd−3, and Pt−3

Electronic and vibrational structure of transition metal trimers: Photoelectron spectra of Ni−3, Pd−3, and Pt−3

10.1063/1.454791

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The transition metal trimer anions Ni−3, Pd−3, and Pt−3 are prepared in a flowing afterglow ion source with a cold cathode dc discharge. The low-lying electronic states of the neutral trimers are probed by 488 nm negative ion photoelectron spectroscopy at an electron kinetic energy resolution of 5–12 meV. Each trimer exhibits multiple low-lying electronic states. Vibrational progressions are observed in tripalladium and triplatinum. The adiabatic electron affinities are found to be EA(Ni3)=1.41±0.05 eV, EA(Pd3)≲1.5±0.1 eV, and EA (Pt3)=1.87±0.02 eV.

Bibliography

Ervin, K. M., Ho, J., & Lineberger, W. C. (1988). Electronic and vibrational structure of transition metal trimers: Photoelectron spectra of Niâ3, Pdâ3, and Ptâ3. The Journal of Chemical Physics, 89(8), 4514â4521.

Authors 3

Kent M. Ervin (first)
Joe Ho (additional)
W. C. Lineberger (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:21 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 3:37 a.m.)
Indexed	1 month, 3 weeks ago (June 30, 2025, 7:26 a.m.)
Issued	36 years, 10 months ago (Oct. 15, 1988)
Published	36 years, 10 months ago (Oct. 15, 1988)
Published Print	36 years, 10 months ago (Oct. 15, 1988)

Funders 0

None

BibTeX

@article{Ervin_1988, title={Electronic and vibrational structure of transition metal trimers: Photoelectron spectra of Ni−3, Pd−3, and Pt−3}, volume={89}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.454791}, DOI={10.1063/1.454791}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Ervin, Kent M. and Ho, Joe and Lineberger, W. C.}, year={1988}, month=oct, pages={4514–4521} }

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