Photophysics of buckminsterfullerene and other carbon cluster ions
10.1063/1.454640
Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

The laser-induced fragmentation behavior of positive carbon cluster ions has been investigated by tandem time-of-flight techniques for the jet-cooled clusters up to 80 atoms in size. Two distinct photophysical regimes were found. The first applies to clusters with 34 atoms or more, all of which dissociate to produce even numbered fragments. Large even clusters fragment by the loss of the high energy species C2, odd ones lose a C atom. The second regime applies to clusters composed of 31 or less atoms, all of which fragment by the loss of C3. These two regimes are sharply separated by C+32 which fragments to produce small cluster ions in the 10–19 atom size range. Fragmentation of the large clusters occurs on a microsecond or faster time scale only at very high levels of excitation (>12.8 eV). These photophysical results are interpreted as consequences of the large even clusters having edgeless, spheroidal cage structures while the small ones have linear chain or ring structures.

Bibliography

O’Brien, S. C., Heath, J. R., Curl, R. F., & Smalley, R. E. (1988). Photophysics of buckminsterfullerene and other carbon cluster ions. The Journal of Chemical Physics, 88(1), 220–230.

Authors 4
  1. S. C. O’Brien (first)
  2. J. R. Heath (additional)
  3. R. F. Curl (additional)
  4. R. E. Smalley (additional)
References 45 Referenced 486
  1. {'key': '2024021005393536700_r1'}
  2. 10.1063/1.447994 / J. Chem. Phys. (1984)
  3. 10.1063/1.450354 / J. Chem. Phys. (1986)
  4. 10.1063/1.451946 / J. Chem. Phys. (1987)
  5. 10.1038/318162a0 / Nature (1985)
  6. 10.1021/j100276a001 / J. Phys. Chem. (1986)
  7. 10.1021/ja00311a102 / J. Am. Chem. Soc. (1985)
  8. 10.1016/S0009-2614(86)80042-2 / Chem. Phys. Lett. (1986)
  9. {'key': '2024021005393536700_r6a', 'first-page': '99', 'volume': '132', 'year': '1987', 'journal-title': 'Chem. Phys. Lett.'} / Chem. Phys. Lett. (1987)
  10. 10.1021/ja00236a012 / J. Am. Chem. Soc. (1987)
  11. {'key': '2024021005393536700_r8'}
  12. 10.1016/S0009-2614(86)80078-1 / Chem. Phys. Lett. (1986)
  13. 10.1016/0009-2614(86)80416-X / Chem. Phys. Lett. (1986)
  14. 10.1016/0009-2614(87)87124-5 / Chem. Phys. Lett. (1987)
  15. {'key': '2024021005393536700_r12', 'first-page': '95', 'volume': '3', 'year': '1986', 'journal-title': 'Z. Phys. D'} / Z. Phys. D (1986)
  16. 10.1021/ja00269a060 / J. Am. Chem. Soc. (1986)
  17. 10.1021/ja01526a010 / J. Am. Chem. Soc. (1959)
  18. 10.1016/0040-4020(66)80020-0 / Tetrahedron (1966)
  19. 10.1007/BF00551119 / Theor. Chim. Acta (1981)
  20. 10.1016/0009-2614(85)87239-0 / Chem. Phys. Lett. (1985)
  21. 10.1021/ja00262a035 / J. Am. Chem. Soc. (1986)
  22. 10.1016/0009-2614(86)87079-8 / Chem. Phys. Lett. (1986)
  23. 10.1021/ja00269a068 / J. Am. Chem. Soc. (1986)
  24. 10.1021/ja00266a032 / J. Am. Chem. Soc. (1986)
  25. 10.1016/0009-2614(86)80455-9 / Chem. Phys. Lett. (1986)
  26. {'key': '2024021005393536700_r20b'}
  27. 10.1016/0009-2614(86)87080-4 / Chem. Phys. Lett. (1986)
  28. 10.1016/S0009-2614(86)80212-3 / Chem. Phys. Lett. (1986)
  29. 10.1016/0009-2614(86)80661-3 / Chem. Phys. Lett. (1986)
  30. 10.1021/ja00279a094 / J. Am. Chem. Soc. (1986)
  31. 10.1016/0009-2614(86)80630-3 / Chem. Phys. Lett. (1986)
  32. {'key': '2024021005393536700_r26', 'first-page': '357', 'volume': '135', 'year': '1986', 'journal-title': 'Chem. Phys. Lett.'} / Chem. Phys. Lett. (1986)
  33. 10.1063/1.452879 / J. Chem. Phys. (1987)
  34. 10.1016/0009-2614(87)80548-1 / Chem. Phys. Lett. (1987)
  35. 10.1063/1.450289 / J. Chem. Phys. (1986)
  36. 10.1063/1.450069 / J. Chem. Phys. (1986)
  37. 10.1063/1.449090 / J. Chem. Phys. (1985)
  38. 10.1016/0009-2614(85)87149-9 / Chem. Phys. Lett. (1985)
  39. 10.1063/1.1715212 / Rev. Sci. Instrum. (1955)
  40. 10.1063/1.451589 / J. Chem. Phys. (1986)
  41. 10.1086/165065 / Astrophys. J. (1987)
  42. {'key': '2024021005393536700_r36', 'first-page': '3', 'volume': 'XIII', 'year': '1987', 'journal-title': 'Comments Condensed Matter Phys.'} / Comments Condensed Matter Phys. (1987)
  43. 10.1063/1.451444 / J. Chem. Phys. (1986)
  44. 10.1063/1.453145 / J. Chem. Phys. (1987)
  45. {'key': '2024021005393536700_r38'}
Dates
Type When
Created 23 years, 1 month ago (July 26, 2002, 9:20 a.m.)
Deposited 1 year, 6 months ago (Feb. 10, 2024, 2:14 a.m.)
Indexed 3 months, 4 weeks ago (May 3, 2025, 3:04 p.m.)
Issued 37 years, 8 months ago (Jan. 1, 1988)
Published 37 years, 8 months ago (Jan. 1, 1988)
Published Print 37 years, 8 months ago (Jan. 1, 1988)
Funders 0

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@article{O_Brien_1988, title={Photophysics of buckminsterfullerene and other carbon cluster ions}, volume={88}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.454640}, DOI={10.1063/1.454640}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={O’Brien, S. C. and Heath, J. R. and Curl, R. F. and Smalley, R. E.}, year={1988}, month=jan, pages={220–230} }