DOI: 10.1063/1.454219. What is the solvent longitudinal time scale controlling electron transfer rates?

What is the solvent longitudinal time scale controlling electron transfer rates?

10.1063/1.454219

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

A theory for electron transfer rates in polar solvents is developed using an expansion of the density matrix in Liouville space and utilizing the analogy with the problem of nonlinear optical line shapes. The relevant solvent longitudinal time scale which controls the rate and the adiabaticity of electron transfer processes is precisely defined in terms of the solvent dielectric function ε(ω) for an arbitrary non-Debye solvent.

Bibliography

Sparpaglione, M., & Mukamel, S. (1988). What is the solvent longitudinal time scale controlling electron transfer rates? The Journal of Chemical Physics, 88(2), 1465â1466.

Authors 2

Massimo Sparpaglione (first)
Shaul Mukamel (additional)

References 22 Referenced 25

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:20 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 2:16 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 4:44 a.m.)
Issued	37 years, 7 months ago (Jan. 15, 1988)
Published	37 years, 7 months ago (Jan. 15, 1988)
Published Print	37 years, 7 months ago (Jan. 15, 1988)

Funders 0

None

BibTeX

@article{Sparpaglione_1988, title={What is the solvent longitudinal time scale controlling electron transfer rates?}, volume={88}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.454219}, DOI={10.1063/1.454219}, number={2}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Sparpaglione, Massimo and Mukamel, Shaul}, year={1988}, month=jan, pages={1465–1466} }

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