DOI: 10.1063/1.453925. Resonance-like phenomena in activated dissociative adsorption: N+2 on Ni(100) and Ni(111)

Resonance-like phenomena in activated dissociative adsorption: N+2 on Ni(100) and Ni(111)

10.1063/1.453925

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Atomic nitrogen adsorption on Ni(100) and Ni(111) surfaces was studied by using very low energy (1–20 eV) N+2 and N+ ion beams. The amount of adsorbed nitrogen was measured by Auger electron spectroscopy as a function of the incident energy of the ions. The adsorption rate for N+ is almost a constant, whereas the dissociative-adsorption rate for N+2 is strongly energy dependent. In the latter case, there exist two channels; one has a low apparent activation barrier of about 1 eV and the other of about 5 eV. A resonance-like feature in the low-activation-barrier reaction was observed at the incident energy of 2–3 eV on Ni(100) and ∼4 eV on Ni(111). The adsorption rate is independent of the angle of incidence. The resonance-like feature is explained by a model which assumes that electronically excited molecules produced by resonance neutralization of the incident ions are dissociatively adsorbed over the low activation barrier and the excited molecules are deexcited on the surface at higher incident energies.

Bibliography

Akazawa, H., & Murata, Y. (1988). Resonance-like phenomena in activated dissociative adsorption: N+2 on Ni(100) and Ni(111). The Journal of Chemical Physics, 88(5), 3317â3321.

Authors 2

Housei Akazawa (first)
Yoshitada Murata (additional)

References 42 Referenced 28

10.1063/1.444847 / J. Chem. Phys. (1983)
10.1103/PhysRevLett.43.1175 / Phys. Rev. Lett. (1979)
10.1063/1.449455 / J. Chem. Phys. (1985)
10.1016/0039-6028(77)90105-4 / Surf. Sci. (1977)
10.1016/0039-6028(81)90360-5 / Surf. Sci. (1981)
10.1016/0039-6028(75)90092-8 / Surf. Sci. (1975)
10.1016/0039-6028(83)90490-9 / Surf. Sci. (1983)
10.1016/0039-6028(85)90671-5 / Surf. Sci. (1985)
10.1103/PhysRevLett.52.2183 / Phys. Rev. Lett. (1984)
10.1016/0039-6028(86)90586-8 / Surf. Sci. (1986)
10.1016/0168-583X(86)90072-8 / Nucl. Instrum. Methods B (1986)
10.1016/0039-6028(71)90214-7 / Surf. Sci. (1971)
10.1016/0039-6028(79)90624-1 / Surf. Sci. (1979)
10.1016/0021-9517(80)90280-8 / J. Catal. (1980)
10.1063/1.1726879 / J. Chem. Phys. (1966)
10.1016/0039-6028(74)90315-X / Surf. Sci. (1974)
10.1016/0039-6028(85)90407-8 / Surf. Sci. (1985)
10.1021/j100271a014 / J. Phys. Chem. (1985)
10.1103/PhysRevLett.54.2716 / Phys. Rev. Lett. (1985)
10.1063/1.451211 / J. Chem. Phys. (1986)
10.1016/0039-6028(87)90118-X / Surf. Sci. (1987)
10.1063/1.452442 / J. Chem. Phys. (1987)
10.1063/1.451310 / J. Chem. Phys. (1986)
10.1103/PhysRevLett.58.1691 / Phys. Rev. Lett. (1987)
10.1016/0039-6028(86)90717-X / Surf. Sci. (1986)
10.1016/0039-6028(84)90564-8 / Surf. Sci. (1984)
10.1063/1.447915 / J. Chem. Phys. (1984)
10.1063/1.451334 / J. Chem. Phys. (1986)
10.1063/1.448645 / J. Chem. Phys. (1985)
10.1016/0009-2614(84)85688-2 / Chem. Phys. Lett. (1984)
10.1016/0009-2614(81)80174-1 / Chem. Phys. Lett. (1981)
10.1016/0378-5963(82)90070-8 / Appl. Surf. Sci. (1982)
10.1016/0039-6028(84)90153-5 / Surf. Sci. (1984)
10.1063/1.442998 / J. Chem. Phys. (1982)
10.1016/0039-6028(86)90034-8 / Surf. Sci. (1986)
10.1063/1.1683697 / Rev. Sci. Instrum. (1969)
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10.1103/PhysRevLett.53.2031 / Phys. Rev. Lett. (1984)
{'key': '2024021005502690900_r31'}
10.1016/0029-554X(82)90596-1 / Nucl. Instrum. Methods (1982)
10.1103/PhysRev.178.76 / Phys. Rev. (1969)
10.1016/0301-0104(82)85071-4 / Chem. Phys. (1982)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:20 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 2:25 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 3:05 p.m.)
Issued	37 years, 5 months ago (March 1, 1988)
Published	37 years, 5 months ago (March 1, 1988)
Published Print	37 years, 5 months ago (March 1, 1988)

Funders 0

None

BibTeX

@article{Akazawa_1988, title={Resonance-like phenomena in activated dissociative adsorption: N+2 on Ni(100) and Ni(111)}, volume={88}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.453925}, DOI={10.1063/1.453925}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Akazawa, Housei and Murata, Yoshitada}, year={1988}, month=mar, pages={3317–3321} }

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