DOI: 10.1063/1.453920. Dynamics of ionic solvation

10.1063/1.453920

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Dynamics of solvation in simple polar liquids is studied within the framework of the mean spherical approximation. Exact results are derived for the Born solvation energy and for the correlation function for the solvation time of an instantaneously formed ion (or dipole) in a polar solvent. The results are in qualitative agreement with the recent approximate treatment by P. Wolynes [J. Chem. Phys. 86, 5133 (1987)]. Implications of the results for the solvation dynamics of dipoles and of excess electrons in polar solvents are considered.

Bibliography

Rips, I., Klafter, J., & Jortner, J. (1988). Dynamics of ionic solvation. The Journal of Chemical Physics, 88(5), 3246â3252.

Authors 3

Ilya Rips (first)
Joseph Klafter (additional)
Joshua Jortner (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:10 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 2:32 a.m.)
Indexed	1 month, 3 weeks ago (July 2, 2025, 1:11 p.m.)
Issued	37 years, 5 months ago (March 1, 1988)
Published	37 years, 5 months ago (March 1, 1988)
Published Print	37 years, 5 months ago (March 1, 1988)

Funders 0

None

BibTeX

@article{Rips_1988, title={Dynamics of ionic solvation}, volume={88}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.453920}, DOI={10.1063/1.453920}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Rips, Ilya and Klafter, Joseph and Jortner, Joshua}, year={1988}, month=mar, pages={3246–3252} }

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