DOI: 10.1063/1.453916. Numerical solution of two new integral equations for the electrical double layer

Numerical solution of two new integral equations for the electrical double layer

10.1063/1.453916

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We report the numerical solution of two new integral equations for the diffused electrical double layer referred to as WLMB/MSA and WLMB/HNC. The WLMB/MSA uses the homogeneous bulk MSA approximation for the direct correlation function and predicts surface potentials that fare within 5% of the reported Monte Carlo data. The effect of the ionic diameter on the surface potential is studied and a behavior similar to that reported for the HNC/MSA is found. The use of the HNC approximation for the bulk electrolyte direct correlation function improves the description of the density profile for a high concentraiton but gives poor results for low concentrations.

Bibliography

Colmenares, P. J., & Olivares, W. (1988). Numerical solution of two new integral equations for the electrical double layer. The Journal of Chemical Physics, 88(5), 3221â3226.

Authors 2

Pedro J. Colmenares (first)
Wilmer Olivares (additional)

References 26 Referenced 7

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{'key': '2024021005595473700_r5'}
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:20 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 2:36 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 9:01 p.m.)
Issued	37 years, 6 months ago (March 1, 1988)
Published	37 years, 6 months ago (March 1, 1988)
Published Print	37 years, 6 months ago (March 1, 1988)

Funders 0

None

BibTeX

@article{Colmenares_1988, title={Numerical solution of two new integral equations for the electrical double layer}, volume={88}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.453916}, DOI={10.1063/1.453916}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Colmenares, Pedro J. and Olivares, Wilmer}, year={1988}, month=mar, pages={3221–3226} }

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