DOI: 10.1063/1.453710. The density of supercooled water. II. Bulk samples cooled to the homogeneous nucleation limit

The density of supercooled water. II. Bulk samples cooled to the homogeneous nucleation limit

10.1063/1.453710

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

We have measured the density of supercooled water (H2O) in the range −33.41≤T≤−5.23 °C. Our samples were held in glass capillary tubing with an approximate inside diameter of 0.3 mm=300 μ. These samples were prepared by Mossop’s method and could be cooled to their homogeneous nucleation limit before freezing. We compare our density data to other measurements using capillaries and demonstrate what appears to be an excess density in smaller capillaries which is inversely proportional to the capillary inside diameter. The origins of this excess density are unknown, but we show its effect is insignificant on our measurement. The thermal expansivities derived from our data are fit to a power law in temperature relative to a singular temperature. These results are inconclusive due to a poor knowledge of the background expansivity.

Bibliography

Hare, D. E., & Sorensen, C. M. (1987). The density of supercooled water. II. Bulk samples cooled to the homogeneous nucleation limit. The Journal of Chemical Physics, 87(8), 4840â4845.

Authors 2

D. E. Hare (first)
C. M. Sorensen (additional)

References 19 Referenced 202

10.1063/1.433153 / J. Chem. Phys. (1976)
{'key': '2024021005314941100_r2'}
10.1146/annurev.pc.34.100183.003113 / Annu. Rev. Phys. Chem. (1983)
10.1063/1.448417 / J. Chem. Phys. (1985)
10.1063/1.450660 / J. Chem. Phys. (1986)
10.1088/0370-1301/68/4/301 / Proc. Phys. Soc. London Sect. B (1955)
10.1021/je60032a018 / J. Chem. Eng. Data (1967)
10.1029/JZ072i012p03271 / J. Geophys. Res. (1967)
{'key': '2024021005314941100_r9', 'first-page': '950', 'volume': '42', 'year': '1968', 'journal-title': 'Russian J. Phys. Chem.'} / Russian J. Phys. Chem. (1968)
{'key': '2024021005314941100_r9a', 'first-page': '1311', 'volume': '43', 'year': '1969', 'journal-title': 'Russ. J. Phys. Chem.'} / Russ. J. Phys. Chem. (1969)
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{'key': '2024021005314941100_r11a'}
{'key': '2024021005314941100_r12'}
{'key': '2024021005314941100_r13', 'first-page': '279', 'volume': '59', 'year': '1971', 'journal-title': 'Sci. Prog. Oxford'} / Sci. Prog. Oxford (1971)
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:19 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 2:04 a.m.)
Indexed	41 minutes ago (Sept. 3, 2025, 6:17 a.m.)
Issued	37 years, 10 months ago (Oct. 15, 1987)
Published	37 years, 10 months ago (Oct. 15, 1987)
Published Print	37 years, 10 months ago (Oct. 15, 1987)

Funders 0

None

BibTeX

@article{Hare_1987, title={The density of supercooled water. II. Bulk samples cooled to the homogeneous nucleation limit}, volume={87}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.453710}, DOI={10.1063/1.453710}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hare, D. E. and Sorensen, C. M.}, year={1987}, month=oct, pages={4840–4845} }

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