DOI: 10.1063/1.453467. Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy

Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy

10.1063/1.453467

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The temperature-dependent structure of crystalline methylammoniumtrihalogenoplumbates (II)—CH3NH+3PbX−3 (X=Cl, Br, I)—as determined by x-ray diffraction, is compared with measurements of the temperature-dependent complex permittivity at frequencies of 50–150 GHz. The dielectric measurements reveal a picosecond relaxation process which corresponds to a dynamic disorder of the methylammonium group in the high-temperature phases of the trihalogenoplumbates.

Bibliography

Poglitsch, A., & Weber, D. (1987). Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy. The Journal of Chemical Physics, 87(11), 6373â6378.

Authors 2

A. Poglitsch (first)
D. Weber (additional)

References 12 Referenced 1,444

10.1515/znb-1978-1214 / Z. Naturforsch Teil B (1978)
{'key': '2024021005332717000_r2'}
10.1088/0022-3735/14/8/011 / J. Phys. E (1981)
10.1007/BF01011950 / Int. J. Infrared MM Waves (1985)
{'key': '2024021005332717000_r5'}
{'key': '2024021005332717000_r6'}
{'key': '2024021005332717000_r7'}
10.1063/1.1750906 / J. Chem. Phys. (1941)
10.1002/bip.360250411 / Biopolymers (1986)
10.1002/bip.360220708 / Biopolymers (1983)
10.1016/0022-2836(84)90409-1 / J. Mol. Biol. (1984)
{'key': '2024021005332717000_r12'}

Dates

Type	When
Created	23 years ago (July 26, 2002, 9:10 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 2:06 a.m.)
Indexed	1 day, 6 hours ago (Aug. 23, 2025, 9:28 p.m.)
Issued	37 years, 8 months ago (Dec. 1, 1987)
Published	37 years, 8 months ago (Dec. 1, 1987)
Published Print	37 years, 8 months ago (Dec. 1, 1987)

Funders 0

None

BibTeX

@article{Poglitsch_1987, title={Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy}, volume={87}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.453467}, DOI={10.1063/1.453467}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Poglitsch, A. and Weber, D.}, year={1987}, month=dec, pages={6373–6378} }

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