DOI: 10.1063/1.453434. Outer sphere electron transfer in polar solvents. Activationless and inverted regimes

Outer sphere electron transfer in polar solvents. Activationless and inverted regimes

10.1063/1.453434

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

In this paper we apply the stochastic Liouville equation for the study of outer sphere electron transfer (ET) in a polar solvent, which is characterized by a Debye dielectric relaxation. Explicit expressions, which bridge between the nonadiabatic and solvent-controlled adiabatic limits, are derived for the ET rates spanning a broad range of the energetic parameters, which include normal ET, activationless ET, and ET in the inverted region. The many-body result for the ET rate, which is accurate for symmetric ET, constitutes a useful approximate interpolation formula, which accounts well for the ET dynamics over a broad range of the energetic parameters.

Bibliography

Rips, I., & Jortner, J. (1987). Outer sphere electron transfer in polar solvents. Activationless and inverted regimes. The Journal of Chemical Physics, 87(11), 6513â6519.

Authors 2

Ilya Rips (first)
Joshua Jortner (additional)

References 30 Referenced 163

{'key': '2024021005283883000_r1'}
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:10 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 2 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 8:05 a.m.)
Issued	37 years, 9 months ago (Dec. 1, 1987)
Published	37 years, 9 months ago (Dec. 1, 1987)
Published Print	37 years, 9 months ago (Dec. 1, 1987)

Funders 0

None

BibTeX

@article{Rips_1987, title={Outer sphere electron transfer in polar solvents. Activationless and inverted regimes}, volume={87}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.453434}, DOI={10.1063/1.453434}, number={11}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Rips, Ilya and Jortner, Joshua}, year={1987}, month=dec, pages={6513–6519} }

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