DOI: 10.1063/1.453214. Laser photoelectron spectroscopy of CrH−, CoH−, and NiH−: Periodic trends in the electronic structure of the transition-metal hydrides

Laser photoelectron spectroscopy of CrH−, CoH−, and NiH−: Periodic trends in the electronic structure of the transition-metal hydrides

10.1063/1.453214

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The laser photoelectron spectra of CrH−, CoH−, and NiH− and the analogous deuterides are reported. The spectra are interpreted using a qualitative description of the electronic structure for the hydrides. This model is used to assign off-diagonal transitions in the photodetachment to low-spin states of the neutrals, and diagonal transitions to high-spin states of the neutrals. These data are used to identify the high-spin states of CoH and NiH; several other states of CrH, CoH, and NiH are also identified. Periodic trends in the bond lengths, vibrational frequencies, and electronic excitation energies for the MnH through NiH molecules are examined. Electron affinities are reported for CrH (0.563±0.010 eV), CoH (0.671±0.010 eV), and NiH (0.481±0.007 eV), and the corresponding deuterides.

Bibliography

Stevens Miller, A. E., Feigerle, C. S., & Lineberger, W. C. (1987). Laser photoelectron spectroscopy of CrHâ, CoHâ, and NiHâ: Periodic trends in the electronic structure of the transition-metal hydrides. The Journal of Chemical Physics, 87(3), 1549â1556.

Authors 3

Amy E. Stevens Miller (first)
C. S. Feigerle (additional)
W. C. Lineberger (additional)

References 46 Referenced 49

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:10 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 1:20 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 5:38 a.m.)
Issued	38 years ago (Aug. 1, 1987)
Published	38 years ago (Aug. 1, 1987)
Published Print	38 years ago (Aug. 1, 1987)

Funders 0

None

BibTeX

@article{Stevens_Miller_1987, title={Laser photoelectron spectroscopy of CrH‚àí, CoH‚àí, and NiH‚àí: Periodic trends in the electronic structure of the transition-metal hydrides}, volume={87}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.453214}, DOI={10.1063/1.453214}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Stevens Miller, Amy E. and Feigerle, C. S. and Lineberger, W. C.}, year={1987}, month=aug, pages={1549‚Äì1556} }

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