DOI: 10.1063/1.452072. Excitation transport in solution: A quantitative comparison between GAF theory and time-resolved fluorescence profiles

Excitation transport in solution: A quantitative comparison between GAF theory and time-resolved fluorescence profiles

10.1063/1.452072

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Time-correlated single photon counting was used to monitor fluorescence concentration depolarization for DODCI in glycerol. For DODCI concentrations below ∼10−3 M, the present experiments have minimized self-absorption and excitation trapping artifacts to the extent where they contribute negligibly to the observed differences between experimental fluorescence profiles and profiles computed from the Gochanour–Andersen–Fayer three-body theory for excitation transport in solution. The three-body theory accurately describes fluorescence depolarization at the lower dye concentrations. At higher concentrations, the measured decay in Gs(t), the probability that the excitation resides on the laser-excited molecule, is perceptibly slower than predicted by the three-body theory. This deviation may arise from nonrandom dye distributions in solution, rather than from errors in the three-body theory. The experimental decay is equally well described at all concentrations by an earlier analytic theory which was developed by Huber, Hamilton, and Barnett.

Bibliography

Hart, D. E., Anfinrud, P. A., & Struve, W. S. (1987). Excitation transport in solution: A quantitative comparison between GAF theory and time-resolved fluorescence profiles. The Journal of Chemical Physics, 86(5), 2689â2696.

Authors 3

David E. Hart (first)
Philip A. Anfinrud (additional)
Walter S. Struve (additional)

References 21 Referenced 29

10.1039/DF9592700007 / Discuss. Faraday Soc. (1959)
10.1063/1.437999 / J. Chem. Phys. (1979)
{'key': '2024021004355496200_r3', 'first-page': '339', 'volume': '5', 'year': '1950', 'journal-title': 'Tr. Fiz. Inst. Akod. Nauk USSR'} / Tr. Fiz. Inst. Akod. Nauk USSR (1950)
{'key': '2024021004355496200_r4', 'first-page': '13', 'volume': '13', 'year': '1943', 'journal-title': 'JETP'} / JETP (1943)
10.1080/00268977100102681 / Mol. Phys. (1971)
10.1016/0301-0104(85)87090-7 / Chem. Phys. (1985)
10.1063/1.439236 / J. Chem. Phys. (1980)
{'key': '2024021004355496200_r8', 'first-page': '2990', 'volume': '26', 'year': '1984', 'journal-title': 'Fiz. Tverd. Tela (Leningrad)'} / Fiz. Tverd. Tela (Leningrad) (1984)
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10.1016/0009-2614(83)87454-5 / Chem. Phys. Lett. (1983)
{'key': '2024021004355496200_r15'}
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10.1016/0003-2697(74)90312-1 / Anal. Biochem. (1974)
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10.1103/PhysRevB.16.4642 / Phys. Rev. B (1977)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:10 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 12:58 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 10:03 a.m.)
Issued	38 years, 6 months ago (March 1, 1987)
Published	38 years, 6 months ago (March 1, 1987)
Published Print	38 years, 6 months ago (March 1, 1987)

Funders 0

None

BibTeX

@article{Hart_1987, title={Excitation transport in solution: A quantitative comparison between GAF theory and time-resolved fluorescence profiles}, volume={86}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.452072}, DOI={10.1063/1.452072}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hart, David E. and Anfinrud, Philip A. and Struve, Walter S.}, year={1987}, month=mar, pages={2689–2696} }

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