DOI: 10.1063/1.451819. The interphase between jellium and a hard sphere electrolyte: Capacity–charge characteristics and dipole potentials

The interphase between jellium and a hard sphere electrolyte: Capacity–charge characteristics and dipole potentials

10.1063/1.451819

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The jellium/hard sphere electrolyte model for the electric double layer is reconsidered and extended in several ways. The effect of various approximations for the electronic density profile on the calculated capacity values is investigated. On the whole, the new calculations, which are performed with a higher accuracy, confirm our previous results. A heuristic formula for the dielectric response of the ensemble of hard spheres to high electric fields is presented; capacity–charge characteristics calculated from this formula show a capacity maximum close to the potential of zero charge. The dipole potential at the uncharged interface is also calculated; its variation with the metal agrees well with the values derived by Trasatti from experimental data.

Bibliography

Schmickler, W., & Henderson, D. (1986). The interphase between jellium and a hard sphere electrolyte: Capacityâcharge characteristics and dipole potentials. The Journal of Chemical Physics, 85(3), 1650â1657.

Authors 2

Wolfgang Schmickler (first)
Douglas Henderson (additional)

References 38 Referenced 81

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:02 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 11:55 p.m.)
Indexed	1 year, 1 month ago (July 9, 2024, 8:50 p.m.)
Issued	39 years ago (Aug. 1, 1986)
Published	39 years ago (Aug. 1, 1986)
Published Print	39 years ago (Aug. 1, 1986)

Funders 0

None

BibTeX

@article{Schmickler_1986, title={The interphase between jellium and a hard sphere electrolyte: Capacity–charge characteristics and dipole potentials}, volume={85}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.451819}, DOI={10.1063/1.451819}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Schmickler, Wolfgang and Henderson, Douglas}, year={1986}, month=aug, pages={1650–1657} }

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