Abstract
The electron energy loss spectra of gaseous thiophene and thiolane in the regions of S 2p, S 2s, and C 1s are presented along with the x-ray photoelectron yield (NEXAFS) spectra of both gases in the region of S 1s excitation. The thiophene spectra are compared to the corresponding NEXAFS spectra of solid (multilayer) and monolayer thiophene on Pt (111). MS-Xα calculations of the C 1s, S 2p, and S 1s excitation spectra of free thiophene are also reported. Intercomparison of the gas, surface, and calculated spectra allows a complete interpretation of the spectral features and facilitates determination of the molecular orientation of thiophene with respect to the surface in both the compressed [thiophene on Pt (111) at 150 K] and relaxed [thiophene on Pt (111) at 180 K] monolayer phases.
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Dates
Type | When |
---|---|
Created | 23 years, 1 month ago (July 26, 2002, 9:02 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 10, 2024, 12:10 a.m.) |
Indexed | 2 days ago (Sept. 3, 2025, 6:06 a.m.) |
Issued | 38 years, 10 months ago (Nov. 1, 1986) |
Published | 38 years, 10 months ago (Nov. 1, 1986) |
Published Print | 38 years, 10 months ago (Nov. 1, 1986) |
@article{Hitchcock_1986, title={Inner shell excitation of thiophene and thiolane: Gas, solid, and monolayer states}, volume={85}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.451718}, DOI={10.1063/1.451718}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hitchcock, A. P. and Horsley, J. A. and Stöhr, J.}, year={1986}, month=nov, pages={4835–4848} }