Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

The electron energy loss spectra of gaseous thiophene and thiolane in the regions of S 2p, S 2s, and C 1s are presented along with the x-ray photoelectron yield (NEXAFS) spectra of both gases in the region of S 1s excitation. The thiophene spectra are compared to the corresponding NEXAFS spectra of solid (multilayer) and monolayer thiophene on Pt (111). MS-Xα calculations of the C 1s, S 2p, and S 1s excitation spectra of free thiophene are also reported. Intercomparison of the gas, surface, and calculated spectra allows a complete interpretation of the spectral features and facilitates determination of the molecular orientation of thiophene with respect to the surface in both the compressed [thiophene on Pt (111) at 150 K] and relaxed [thiophene on Pt (111) at 180 K] monolayer phases.

Bibliography

Hitchcock, A. P., Horsley, J. A., & Stöhr, J. (1986). Inner shell excitation of thiophene and thiolane: Gas, solid, and monolayer states. The Journal of Chemical Physics, 85(9), 4835–4848.

Authors 3
  1. A. P. Hitchcock (first)
  2. J. A. Horsley (additional)
  3. J. Stöhr (additional)
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Dates
Type When
Created 23 years, 1 month ago (July 26, 2002, 9:02 a.m.)
Deposited 1 year, 6 months ago (Feb. 10, 2024, 12:10 a.m.)
Indexed 2 days ago (Sept. 3, 2025, 6:06 a.m.)
Issued 38 years, 10 months ago (Nov. 1, 1986)
Published 38 years, 10 months ago (Nov. 1, 1986)
Published Print 38 years, 10 months ago (Nov. 1, 1986)
Funders 0

None

@article{Hitchcock_1986, title={Inner shell excitation of thiophene and thiolane: Gas, solid, and monolayer states}, volume={85}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.451718}, DOI={10.1063/1.451718}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hitchcock, A. P. and Horsley, J. A. and Stöhr, J.}, year={1986}, month=nov, pages={4835–4848} }