DOI: 10.1063/1.451646. Rotational analysis and vibrational predissociation in the ν2 band of HCN dimer

Rotational analysis and vibrational predissociation in the ν2 band of HCN dimer

10.1063/1.451646

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The rovibrational infrared spectrum of the bound C–H stretching vibration, ν2, in the HCN dimer has been analyzed. Observed transition frequencies have been combined with previously recorded microwave data to obtain the following molecular parameters (in cm−1): ν2=3241.5696(8), α2=−0.000 110(1), B″=0.058 233 92(1), B′=0.058 344(1), D″J =0.7013(52)×10−7, DJ =0.6636(18)×10−7. The observed full widths at half-maximum intensity of the observed transitions are consistent with excited state lifetimes of 1.7(4)×10−9 s.

Bibliography

Wofford, B. A., Bevan, J. W., Olson, W. B., & Lafferty, W. J. (1986). Rotational analysis and vibrational predissociation in the Î½2 band of HCN dimer. The Journal of Chemical Physics, 85(1), 105â108.

Authors 4

B. A. Wofford (first)
J. W. Bevan (additional)
W. B. Olson (additional)
W. J. Lafferty (additional)

References 17 Referenced 42

10.1086/154986 / Astrophys. J. (1977)
{'key': '2024021003290157100_r2', 'first-page': '89', 'volume': '19', 'year': '1978', 'journal-title': 'Astrophys. Lett.'} / Astrophys. Lett. (1978)
10.1021/ja00838a001 / J. Am. Chem. Soc. (1975)
10.1007/BF00527658 / Theor. Chim. Acta (1972)
10.1098/rspa.1985.0063 / Proc. R. Soc. London Ser. A (1985)
{'key': '2024021003290157100_r6', 'first-page': '352', 'volume': '89', 'year': '1977', 'journal-title': 'J. Mol. Spectrosc.'} / J. Mol. Spectrosc. (1977)
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{'key': '2024021003290157100_r13'}
{'key': '2024021003290157100_r14', 'first-page': '3558', 'volume': '78', 'year': '1983', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1983)
10.1016/0009-2614(85)80578-9 / Chem. Phys. Lett. (1985)
{'key': '2024021003290157100_r16'}

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 11:46 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6:46 a.m.)
Issued	39 years, 2 months ago (July 1, 1986)
Published	39 years, 2 months ago (July 1, 1986)
Published Print	39 years, 2 months ago (July 1, 1986)

Funders 0

None

BibTeX

@article{Wofford_1986, title={Rotational analysis and vibrational predissociation in the ν2 band of HCN dimer}, volume={85}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.451646}, DOI={10.1063/1.451646}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Wofford, B. A. and Bevan, J. W. and Olson, W. B. and Lafferty, W. J.}, year={1986}, month=jul, pages={105–108} }

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