DOI: 10.1063/1.451376. The argon–hydrogen fluoride binary complex: An example of a long lived metastable system

The argon–hydrogen fluoride binary complex: An example of a long lived metastable system

10.1063/1.451376

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The optothermal laser–molecular beam method has been used to measure the infrared spectrum of Ar–HF [10°0←00°0]. The results show that the vibrational predissociation lifetime of this complex is greater than the flight time of the molecules from the laser crossing region to the bolometer detector. This gives a lower limit on the lifetime of 3×10−4 s! The upper vibrational state dipole moment has also been obtained for the complex (μ1=1.495 D) by carrying out infrared stark spectroscopy. This corresponds to a 12% increase in the dipole moment upon vibrational excitation. This change can be related to a stiffening of the van der Waals bond, and hence a reduction in the amplitude of the bending motion, in the vibrationally excited state.

Bibliography

Huang, Z. S., Jucks, K. W., & Miller, R. E. (1986). The argonâhydrogen fluoride binary complex: An example of a long lived metastable system. The Journal of Chemical Physics, 85(12), 6905â6909.

Authors 3

Z. S. Huang (first)
K. W. Jucks (additional)
R. E. Miller (additional)

References 32 Referenced 112

10.1063/1.438666 / J. Chem. Phys. (1979)
10.1063/1.436732 / J. Chem. Phys. (1978)
{'key': '2024021004131060700_r2a', 'first-page': '252', 'volume': '6', 'year': '1978', 'journal-title': 'Laser Ind. Proc. Mol.'} / Laser Ind. Proc. Mol. (1978)
10.1063/1.446653 / J. Chem. Phys. (1984)
10.1063/1.441712 / J. Chem. Phys. (1981)
10.1063/1.445437 / J. Chem. Phys. (1983)
10.1016/0301-0104(80)87062-5 / Chem. Phys. (1980)
10.1063/1.439304 / J. Chem. Phys. (1980)
10.1063/1.441129 / J. Chem. Phys. (1981)
{'key': '2024021004131060700_r9', 'first-page': '2357', 'volume': '61', 'year': '1984', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1984)
{'key': '2024021004131060700_r9a', 'first-page': '4474', 'volume': '81', 'year': '1964', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1964)
10.1063/1.450167 / J. Chem. Phys. (1986)
10.1063/1.1681508 / J. Chem. Phys. (1974)
10.1063/1.441113 / J. Chem. Phys. (1981)
10.1063/1.441370 / J. Chem. Phys. (1981)
10.1016/0009-2614(86)80298-6 / Chem. Phys. Lett. (1986)
10.1063/1.451059 / J. Chem. Phys. (1986)
{'key': '2024021004131060700_r14'}
10.1080/00268978200100621 / Mol. Phys. (1982)
10.1080/00268978400101541 / Mol. Phys. (1984)
{'key': '2024021004131060700_r17'}
{'key': '2024021004131060700_r18'}
10.1063/1.443631 / J. Chem. Phys. (1982)
10.1021/j150654a016 / J. Phys. Chem. (1984)
{'key': '2024021004131060700_r21'}
10.1039/dc9817100077 / Faraday Discuss. Chem. Soc. (1981)
10.1063/1.1672903 / J. Chem. Phys. (1970)
10.1063/1.1677052 / J. Chem. Phys. (1972)
10.1063/1.442322 / J. Chem. Phys. (1981)
10.1016/S0092-640X(74)80028-8 / At. Data Nucl. Data Tables (1974)
10.1063/1.445078 / J. Chem. Phys. (1983)
10.1063/1.448043 / J. Chem. Phys. (1984)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:02 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 12:32 a.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 7:26 a.m.)
Issued	38 years, 8 months ago (Dec. 15, 1986)
Published	38 years, 8 months ago (Dec. 15, 1986)
Published Print	38 years, 8 months ago (Dec. 15, 1986)

Funders 0

None

BibTeX

@article{Huang_1986, title={The argon–hydrogen fluoride binary complex: An example of a long lived metastable system}, volume={85}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.451376}, DOI={10.1063/1.451376}, number={12}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Huang, Z. S. and Jucks, K. W. and Miller, R. E.}, year={1986}, month=dec, pages={6905–6909} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        2,
        11
      ]
    ],
    "date-time": "2024-02-11T12:26:04Z",
    "timestamp": 1707654364183
  },
  "reference-count": 32,
  "publisher": "AIP Publishing",
  "issue": "12",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1986,
        12,
        15
      ]
    ]
  },
  "abstract": "<jats:p>The optothermal laser\u2013molecular beam method has been used to measure the infrared spectrum of Ar\u2013HF [10\u00b00\u219000\u00b00]. The results show that the vibrational predissociation lifetime of this complex is greater than the flight time of the molecules from the laser crossing region to the bolometer detector. This gives a lower limit on the lifetime of 3\u00d710\u22124 s! The upper vibrational state dipole moment has also been obtained for the complex (\u03bc1=1.495 D) by carrying out infrared stark spectroscopy. This corresponds to a 12% increase in the dipole moment upon vibrational excitation. This change can be related to a stiffening of the van der Waals bond, and hence a reduction in the amplitude of the bending motion, in the vibrationally excited state.</jats:p>",
  "DOI": "10.1063/1.451376",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T13:02:54Z",
    "timestamp": 1027688574000
  },
  "page": "6905-6909",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 112,
  "title": "The argon\u2013hydrogen fluoride binary complex: An example of a long lived metastable system",
  "prefix": "10.1063",
  "volume": "85",
  "author": [
    {
      "given": "Z. S.",
      "family": "Huang",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27514"
        }
      ]
    },
    {
      "given": "K. W.",
      "family": "Jucks",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27514"
        }
      ]
    },
    {
      "given": "R. E.",
      "family": "Miller",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27514"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024021004131060700_r1",
      "doi-asserted-by": "crossref",
      "first-page": "3143",
      "DOI": "10.1063/1.438666",
      "volume": "71",
      "year": "1979",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r2",
      "doi-asserted-by": "crossref",
      "first-page": "1588",
      "DOI": "10.1063/1.436732",
      "volume": "69",
      "year": "1978",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r2a",
      "first-page": "252",
      "volume": "6",
      "year": "1978",
      "journal-title": "Laser Ind. Proc. Mol."
    },
    {
      "key": "2024021004131060700_r3",
      "doi-asserted-by": "crossref",
      "first-page": "5453",
      "DOI": "10.1063/1.446653",
      "volume": "80",
      "year": "1984",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r4",
      "doi-asserted-by": "crossref",
      "first-page": "5044",
      "DOI": "10.1063/1.441712",
      "volume": "74",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r5",
      "doi-asserted-by": "crossref",
      "first-page": "5567",
      "DOI": "10.1063/1.445437",
      "volume": "78",
      "year": "1983",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r6",
      "doi-asserted-by": "crossref",
      "first-page": "141",
      "DOI": "10.1016/0301-0104(80)87062-5",
      "volume": "53",
      "year": "1980",
      "journal-title": "Chem. Phys."
    },
    {
      "key": "2024021004131060700_r7",
      "doi-asserted-by": "crossref",
      "first-page": "2096",
      "DOI": "10.1063/1.439304",
      "volume": "72",
      "year": "1980",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r8",
      "doi-asserted-by": "crossref",
      "first-page": "6725",
      "DOI": "10.1063/1.441129",
      "volume": "74",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r9",
      "first-page": "2357",
      "volume": "61",
      "year": "1984",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r9a",
      "first-page": "4474",
      "volume": "81",
      "year": "1964",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r10",
      "doi-asserted-by": "crossref",
      "first-page": "170",
      "DOI": "10.1063/1.450167",
      "volume": "84",
      "year": "1986",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r11",
      "doi-asserted-by": "crossref",
      "first-page": "3208",
      "DOI": "10.1063/1.1681508",
      "volume": "60",
      "year": "1974",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r11a",
      "doi-asserted-by": "crossref",
      "first-page": "6539",
      "DOI": "10.1063/1.441113",
      "volume": "74",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r12",
      "doi-asserted-by": "crossref",
      "first-page": "2133",
      "DOI": "10.1063/1.441370",
      "volume": "74",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r13",
      "doi-asserted-by": "crossref",
      "first-page": "374",
      "DOI": "10.1016/0009-2614(86)80298-6",
      "volume": "127",
      "year": "1986",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021004131060700_r13a",
      "doi-asserted-by": "crossref",
      "first-page": "2502",
      "DOI": "10.1063/1.451059",
      "volume": "85",
      "year": "1986",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r14"
    },
    {
      "key": "2024021004131060700_r15",
      "doi-asserted-by": "crossref",
      "first-page": "791",
      "DOI": "10.1080/00268978200100621",
      "volume": "45",
      "year": "1982",
      "journal-title": "Mol. Phys."
    },
    {
      "key": "2024021004131060700_r16",
      "doi-asserted-by": "crossref",
      "first-page": "763",
      "DOI": "10.1080/00268978400101541",
      "volume": "52",
      "year": "1984",
      "journal-title": "Mol. Phys."
    },
    {
      "key": "2024021004131060700_r17"
    },
    {
      "key": "2024021004131060700_r18"
    },
    {
      "key": "2024021004131060700_r19",
      "doi-asserted-by": "crossref",
      "first-page": "47",
      "DOI": "10.1063/1.443631",
      "volume": "77",
      "year": "1982",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r20",
      "doi-asserted-by": "crossref",
      "first-page": "2004",
      "DOI": "10.1021/j150654a016",
      "volume": "88",
      "year": "1984",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021004131060700_r21"
    },
    {
      "key": "2024021004131060700_r22",
      "doi-asserted-by": "crossref",
      "first-page": "77",
      "DOI": "10.1039/dc9817100077",
      "volume": "71",
      "year": "1981",
      "journal-title": "Faraday Discuss. Chem. Soc."
    },
    {
      "key": "2024021004131060700_r23",
      "doi-asserted-by": "crossref",
      "first-page": "6033",
      "DOI": "10.1063/1.1672903",
      "volume": "52",
      "year": "1970",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r24",
      "doi-asserted-by": "crossref",
      "first-page": "5409",
      "DOI": "10.1063/1.1677052",
      "volume": "56",
      "year": "1972",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r25",
      "doi-asserted-by": "crossref",
      "first-page": "2041",
      "DOI": "10.1063/1.442322",
      "volume": "75",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r26",
      "doi-asserted-by": "crossref",
      "first-page": "21",
      "DOI": "10.1016/S0092-640X(74)80028-8",
      "volume": "14",
      "year": "1974",
      "journal-title": "At. Data Nucl. Data Tables"
    },
    {
      "key": "2024021004131060700_r27",
      "doi-asserted-by": "crossref",
      "first-page": "2154",
      "DOI": "10.1063/1.445078",
      "volume": "78",
      "year": "1983",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021004131060700_r27a",
      "doi-asserted-by": "crossref",
      "first-page": "2939",
      "DOI": "10.1063/1.448043",
      "volume": "81",
      "year": "1984",
      "journal-title": "J. Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/85/12/6905/18962244/6905_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/85/12/6905/18962244/6905_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T05:32:59Z",
    "timestamp": 1707543179000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/85/12/6905/793753/The-argon-hydrogen-fluoride-binary-complex-An"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1986,
        12,
        15
      ]
    ]
  },
  "references-count": 32,
  "journal-issue": {
    "issue": "12",
    "published-print": {
      "date-parts": [
        [
          1986,
          12,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.451376",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1986,
        12,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1986,
        12,
        15
      ]
    ]
  }
}