DOI: 10.1063/1.451157. The reactions of mass selected aluminum cluster ions, Al+<i>n</i> (<i>n</i>=4

The reactions of mass selected aluminum cluster ions, Al+n (n=4–25), with oxygen

10.1063/1.451157

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The reactions between aluminum cluster ions Al+n (n=4–25) with oxygen have been studied using a low energy ion beam apparatus at a center of mass collision energy of 1 eV. Some extraordinary reactions were observed. Oxygen very specifically cleaves the aluminum clusters, Al+n, resulting in Al+n−m cluster ions where m=4, 5 and for the larger clusters 10. Al+ is also an important product ion for clusters with n≤13. No oxygen containing product ions were observed. We suggest that addition of oxygen to the cluster raises the ionization potential and makes AlxO+ and AlxO+2 products energetically unfavorable, thus neutral oxide species are formed.

Bibliography

Jarrold, M. F., & Bower, J. E. (1986). The reactions of mass selected aluminum cluster ions, Al+n (n=4â25), with oxygen. The Journal of Chemical Physics, 85(9), 5373â5375.

Authors 2

Martin F. Jarrold (first)
J. Eric Bower (additional)

References 17 Referenced 55

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{'key': '2024021004032684200_r7'}
10.1063/1.449991 / J. Chem. Phys. (1986)
{'key': '2024021004032684200_r8a'}
10.1103/PhysRevLett.56.2168 / Phys. Rev. Lett. (1986)
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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:08 a.m.)
Deposited	1 year, 6 months ago (Feb. 10, 2024, 12:21 a.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 6:45 p.m.)
Issued	38 years, 9 months ago (Nov. 1, 1986)
Published	38 years, 9 months ago (Nov. 1, 1986)
Published Print	38 years, 9 months ago (Nov. 1, 1986)

Funders 0

None

BibTeX

@article{Jarrold_1986, title={The reactions of mass selected aluminum cluster ions, Al+n (n=4–25), with oxygen}, volume={85}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.451157}, DOI={10.1063/1.451157}, number={9}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Jarrold, Martin F. and Bower, J. Eric}, year={1986}, month=nov, pages={5373–5375} }

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