Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

Raman spectra of H2O and D2O ice VIII have been measured up to 50 GPa at 100 K. The changes in line positions and intensities of ice VIII and the appearance of a new band above 40 GPa point to the formation of symmetric hydrogen bonds in ice X. A lattice dynamical analysis of the frequency shifts up to 36 GPa suggest a second order phase transition to symmetric hydrogen bonds near 47.5 GPa. However, the observed changes in the lattice modes indicate that this phase transition is already formed by a first order transition at 42 GPa.

Bibliography

Hirsch, K. R., & Holzapfel, W. B. (1986). Effect of high pressure on the Raman spectra of ice VIII and evidence for ice X. The Journal of Chemical Physics, 84(5), 2771–2775.

Authors 2
  1. K. R. Hirsch (first)
  2. W. B. Holzapfel (additional)
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Dates
Type When
Created 23 years ago (July 26, 2002, 9:08 a.m.)
Deposited 1 year, 6 months ago (Feb. 9, 2024, 11:17 p.m.)
Indexed 1 year, 1 month ago (July 13, 2024, 10:58 p.m.)
Issued 39 years, 5 months ago (March 1, 1986)
Published 39 years, 5 months ago (March 1, 1986)
Published Print 39 years, 5 months ago (March 1, 1986)
Funders 0

None

@article{Hirsch_1986, title={Effect of high pressure on the Raman spectra of ice VIII and evidence for ice X}, volume={84}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.450302}, DOI={10.1063/1.450302}, number={5}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hirsch, K. R. and Holzapfel, W. B.}, year={1986}, month=mar, pages={2771–2775} }