DOI: 10.1063/1.450116. Viscoelastic relaxation of segment orientation in dilute polymer solutions. II. Stiffness dependence of fluorescence depolarization

Viscoelastic relaxation of segment orientation in dilute polymer solutions. II. Stiffness dependence of fluorescence depolarization

10.1063/1.450116

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The memory functions for the orientation of a segment in any position on a linear chain are calculated for a diffusion Gaussian model in the optimized Rouse–Zimm approximation for semiflexible polymer models. The crossover from flexible to rod chains is described and expectations for fluorescence anisotropy, fluorescence quenching, and the mean orientational relaxation time are outlined and discussed.

Bibliography

Perico, A., & Guenza, M. (1986). Viscoelastic relaxation of segment orientation in dilute polymer solutions. II. Stiffness dependence of fluorescence depolarization. The Journal of Chemical Physics, 84(1), 510â516.

Authors 2

Angelo Perico (first)
Marina Guenza (additional)

References 18 Referenced 41

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{'key': '2024021002415351300_r4', 'first-page': '29', 'volume': '14', 'year': '1976', 'journal-title': 'J. Polym. Sci. Polym. Phys. Ed.'} / J. Polym. Sci. Polym. Phys. Ed. (1976)
{'key': '2024021002415351300_r5', 'first-page': '1', 'volume': '15', 'year': '1977', 'journal-title': 'J. Polym. Sci. Polym. Phys. Ed.'} / J. Polym. Sci. Polym. Phys. Ed. (1977)
10.1063/1.449216 / J. Chem. Phys. (1985)
10.1063/1.435915 / J. Chem. Phys. (1978)
{'key': '2024021002415351300_r8', 'first-page': '6281', 'volume': '17', 'year': '1984', 'journal-title': 'Macromolecules'} / Macromolecules (1984)
{'key': '2024021002415351300_r9', 'first-page': '11', 'volume': '14', 'year': '1976', 'journal-title': 'J. Polym. Sci. Polym. Phys. Ed.'} / J. Polym. Sci. Polym. Phys. Ed. (1976)
10.1051/jcp/196966s21865 / J. Chim. Phys. (1969)
10.1002/pol.1975.180130401 / J. Polym. Sci. Polym. Phys. Ed. (1975)
10.1002/pol.1975.180130402 / J. Polym. Sci. Polym. Phys. Ed. (1975)
10.1063/1.1681433 / J. Chem. Phys. (1974)
{'key': '2024021002415351300_r14', 'first-page': '1682', 'volume': '21', 'year': '1980', 'journal-title': 'Polym. Sci. USSR'} / Polym. Sci. USSR (1980)
10.1063/1.449296 / J. Chem. Phys. (1985)
{'key': '2024021002415351300_r16'}
{'key': '2024021002415351300_r17'}
10.1063/1.439352 / J. Chem. Phys. (1980)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 11 p.m.)
Indexed	3 months, 2 weeks ago (May 14, 2025, 10:47 a.m.)
Issued	39 years, 8 months ago (Jan. 1, 1986)
Published	39 years, 8 months ago (Jan. 1, 1986)
Published Print	39 years, 8 months ago (Jan. 1, 1986)

Funders 0

None

BibTeX

@article{Perico_1986, title={Viscoelastic relaxation of segment orientation in dilute polymer solutions. II. Stiffness dependence of fluorescence depolarization}, volume={84}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.450116}, DOI={10.1063/1.450116}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Perico, Angelo and Guenza, Marina}, year={1986}, month=jan, pages={510–516} }

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