Crossref journal-article
AIP Publishing
The Journal of Chemical Physics (317)
Abstract

Crossed molecular beam experiments on state-resolved vibrational excitation of S0 p-difluorobenzene show only v=0→1,2 excitation of mode 30, the in-phase bend of the fluorine atoms perpendicular to the benzene plane. This high degree of mode 30 selectivity in transitions from the rotationally cold vibrational ground state suggests that efficient and mode-specific transfer of vibrational energy in collisions of polyatomic molecules need not depend strongly on intramolecular level mixing.

Bibliography

Hall, G., Giese, C. F., & Gentry, W. R. (1985). Vibrational excitation of ground-state p-difluorobenzene in collisions with He. The Journal of Chemical Physics, 83(10), 5343–5344.

Authors 3
  1. Gregory Hall (first)
  2. Clayton F. Giese (additional)
  3. W. Ronald Gentry (additional)
References 17 Referenced 34
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Dates
Type When
Created 23 years, 1 month ago (July 26, 2002, 9:08 a.m.)
Deposited 1 year, 6 months ago (Feb. 9, 2024, 11:02 p.m.)
Indexed 1 year, 6 months ago (Feb. 11, 2024, 6:41 a.m.)
Issued 39 years, 9 months ago (Nov. 15, 1985)
Published 39 years, 9 months ago (Nov. 15, 1985)
Published Print 39 years, 9 months ago (Nov. 15, 1985)
Funders 0

None

@article{Hall_1985, title={Vibrational excitation of ground-state p-difluorobenzene in collisions with He}, volume={83}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.449699}, DOI={10.1063/1.449699}, number={10}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Hall, Gregory and Giese, Clayton F. and Gentry, W. Ronald}, year={1985}, month=nov, pages={5343–5344} }