DOI: 10.1063/1.449139. Rotational spectra and structure of the ammonia

Rotational spectra and structure of the ammonia–water complex

10.1063/1.449139

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Microwave and radio frequency spectra for NH3⋅H2O and deuterated analogs have been observed by molecular beam electric resonance spectroscopy. Rotational constant, Stark effect, and nitrogen quadrupole coupling interaction data were obtained. This complex is found to have a linear, hydrogen bonded structure with water as the proton donor. The NH3 monomer symmetry axis was found to have a vibrationally averaged displacement of 23.1° from the N...O axis. No evidence for transfer of a proton from water to the ammonia was observed.

Bibliography

Herbine, P., & Dyke, T. R. (1985). Rotational spectra and structure of the ammoniaâwater complex. The Journal of Chemical Physics, 83(8), 3768â3774.

Authors 2

P. Herbine (first)
T. R. Dyke (additional)

References 33 Referenced 104

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Dates

Type	When
Created	23 years ago (July 26, 2002, 9:02 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 10:51 p.m.)
Indexed	1 year ago (Aug. 2, 2024, 2:33 a.m.)
Issued	39 years, 10 months ago (Oct. 15, 1985)
Published	39 years, 10 months ago (Oct. 15, 1985)
Published Print	39 years, 10 months ago (Oct. 15, 1985)

Funders 0

None

BibTeX

@article{Herbine_1985, title={Rotational spectra and structure of the ammonia–water complex}, volume={83}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.449139}, DOI={10.1063/1.449139}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Herbine, P. and Dyke, T. R.}, year={1985}, month=oct, pages={3768–3774} }

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