Abstract
Infrared predissociation spectra of water clusters have been measured in the frequency range 3000–3800 cm−1 using a molecular beam–color center laser apparatus. The transition from a spectrum resembling that of liquid water to that of the dimer is clearly seen. Detailed theoretical analyses using normal mode theory, local mode theory, and a quantum simulation method are used to interpret the spectrum in terms of a potential surface that includes both intramolecular and intermolecular degrees of freedom.
References
46
Referenced
317
10.1063/1.445437
/ J. Chem. Phys. (1983)10.1063/1.441712
/ J. Chem. Phys. (1981)10.1063/1.436732
/ J. Chem. Phys. (1978)10.1021/j150626a018
/ J. Phys. Chem. (1981)10.1016/0301-0104(83)85175-1
/ Chem. Phys. (1983)10.1021/j150650a018
/ J. Phys. Chem. (1984)10.1016/0301-0104(84)85230-1
/ Chem. Phys. (1984){'key': '2024021001575632900_r5', 'first-page': '623', 'volume': '35', 'year': '1983', 'journal-title': 'Aust. J. Phys.'}
/ Aust. J. Phys. (1983)10.1016/0301-0104(84)80055-5
/ Chem. Phys. (1984)10.1016/S0301-0104(84)85175-7
/ Chem. Phys. (1984)10.1063/1.433969
/ J. Chem. Phys. (1977)10.1063/1.1743753
/ J. Chem. Phys. (1957){'key': '2024021001575632900_r8a', 'first-page': '1521', 'volume': '25', 'year': '1970', 'journal-title': 'J. Mol. Spectrosc.'}
/ J. Mol. Spectrosc. (1970)10.1063/1.1673163
/ J. Chem. Phys. (1970)10.1063/1.1679763
/ J. Chem. Phys. (1973)10.1016/0009-2614(75)80260-0
/ Chem. Phys. Lett. (1975)10.1063/1.434478
/ J. Chem. Phys. (1977)10.1021/j100537a011
/ J. Phys. Chem. (1977)10.1016/0022-2852(80)90031-4
/ J. Mol. Spectrosc. (1980)10.1063/1.443631
/ J. Chem. Phys. (1982)10.1063/1.2913824
/ Phys. Today (1980)10.1016/0009-2614(84)85320-8
/ Chem. Phys. Lett. (1984)10.1016/0009-2614(84)80051-2
/ Chem. Phys. Lett. (1984)10.1063/1.446653
/ J. Chem. Phys. (1984)10.1080/00268978400101271
/ Mol. Phys. (1984){'key': '2024021001575632900_r14', 'first-page': '95', 'volume': '64', 'year': '1981', 'journal-title': 'Chem. Phys.'}
/ Chem. Phys. (1981){'key': '2024021001575632900_r15'}
10.1063/1.431514
/ J. Chem. Phys. (1975)10.1063/1.432868
/ J. Chem. Phys. (1976)10.1016/0301-0104(77)85160-4
/ Chem. Phys. (1977)10.1364/JOSA.61.001316
/ J. Opt. Soc. Am. (1971){'key': '2024021001575632900_r18a'}
10.1080/00268977300102121
/ Mol. Phys. (1973)10.1016/0022-2852(74)90177-5
/ J. Mol. Spectrosc. (1974)10.1016/0584-8539(73)80123-0
/ Spectrochim. Acta Part A (1973)10.1016/0022-2852(76)90016-3
/ J. Mol. Spectrosc. (1976)10.1063/1.1743146
/ J. Chem. Phys. (1956){'key': '2024021001575632900_r19e', 'first-page': '294', 'volume': '6', 'year': '1959', 'journal-title': 'Opt. Spectrosc. Congo.'}
/ Opt. Spectrosc. Congo. (1959)10.6028/jres.052.022
/ J. Res. Nat. Bur. Stand. (1954)10.1007/BF01344550
/ Z. Phys. (1933){'key': '2024021001575632900_r20'}
{'key': '2024021001575632900_r20a'}
{'key': '2024021001575632900_r21', 'first-page': '164', 'volume': '324', 'year': '1974', 'journal-title': 'Proc. R. Soc. London Ser. A'}
/ Proc. R. Soc. London Ser. A (1974){'key': '2024021001575632900_r21a', 'first-page': '289', 'volume': '337', 'year': '1975', 'journal-title': 'Proc. R. Soc. London, Ser. A'}
/ Proc. R. Soc. London, Ser. A (1975)10.1016/0022-2852(75)90274-X
/ J. Mol. Spectrosc. (1975)10.1016/0022-2852(76)90026-6
/ J. Mol. Spectrosc. (1976)
Dates
Type | When |
---|---|
Created | 23 years ago (July 26, 2002, 9 a.m.) |
Deposited | 1 year, 6 months ago (Feb. 9, 2024, 10:11 p.m.) |
Indexed | 1 month, 3 weeks ago (June 30, 2025, 7:26 a.m.) |
Issued | 40 years, 4 months ago (April 15, 1985) |
Published | 40 years, 4 months ago (April 15, 1985) |
Published Print | 40 years, 4 months ago (April 15, 1985) |
@article{Coker_1985, title={The infrared predissociation spectra of water clusters}, volume={82}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.448935}, DOI={10.1063/1.448935}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Coker, D. F. and Miller, R. E. and Watts, R. O.}, year={1985}, month=apr, pages={3554–3562} }