DOI: 10.1063/1.448757. Reduction into a rational fraction of a thermodynamic property of the liquid state: Experimental determinations in the case of CO2 and <i>n</i>-butane. Extension to the other properties

Reduction into a rational fraction of a thermodynamic property of the liquid state: Experimental determinations in the case of CO2 and n-butane. Extension to the other properties

10.1063/1.448757

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The expansivity of liquid CO2 and of n-butane is determined as a function of pressure up to 4 kbar, from the melting temperatures up to the critical temperatures. The experimental method is piezothermal. The set of data is processed through a fit with a multipoint Padé approximant using an algorithm due to Werner. This particular technique determines, in its reduced form, the unique rational function relevant to the problem. The expansivity of the whole liquid phase is described in terms of a simple equation with four coefficients which enables calculation of the other thermodynamic properties. The general aspect of the phenomenological equations is discussed in this instance, underlining the particular behavior of the heat capacity as a function of pressure.

Bibliography

Alba, C., Ter Minassian, L., Denis, A., & Soulard, A. (1985). Reduction into a rational fraction of a thermodynamic property of the liquid state: Experimental determinations in the case of CO2 and n-butane. Extension to the other properties. The Journal of Chemical Physics, 82(1), 384â393.

Authors 4

Christiane Alba (first)
Léon Ter Minassian (additional)
Armelle Denis (additional)
Alain Soulard (additional)

References 21 Referenced 43

10.2307/20025445 / Proc. Am. Acad. Arts Sci. (1913)
10.1016/0021-9614(74)90159-1 / J. Chem. Thermodyn. (1974)
10.1051/jcp/1970670265 / J. Chim. Phys. (1970)
10.1063/1.442402 / J. Chem. Phys. (1981)
10.1088/0022-3735/16/5/019 / J. Phys. E (1983)
{'key': '2024021001340070700_r6', 'first-page': '257', 'volume': '76', 'year': '1979', 'journal-title': 'Lectures Notes Math.'} / Lectures Notes Math. (1979)
10.1016/0021-9614(77)90059-3 / J. Chem. Thermodyn. (1977)
{'key': '2024021001340070700_r8'}
{'key': '2024021001340070700_r9'}
{'key': '2024021001340070700_r10'}
{'key': '2024021001340070700_r11'}
{'key': '2024021001340070700_r12', 'volume': '169', 'year': '1982', 'journal-title': 'NBS Monogr.'} / NBS Monogr. (1982)
{'issue': '1', 'key': '2024021001340070700_r13', 'first-page': '33', 'volume': '16', 'year': '1971', 'journal-title': 'Sov. Phys. Dokl.'} / Sov. Phys. Dokl. (1971)
10.1021/ja00406a010 / J. Am. Chem. Soc. (1981)
{'key': '2024021001340070700_r15', 'first-page': '120', 'volume': '18', 'year': '1971', 'journal-title': 'Therm. Eng. (USSR)'} / Therm. Eng. (USSR) (1971)
{'key': '2024021001340070700_r16', 'first-page': '115', 'volume': '72', 'year': '1974', 'journal-title': 'Physical'} / Physical (1974)
10.1021/j100212a038 / J. Phys. Chem. (1982)
10.2307/20023533 / Proc. Am. Acad. Arts Sci. (1949)
10.1080/00268977900101051 / Mol. Phys. (1979)
10.1016/0031-8914(74)90081-0 / Physica (1974)
{'key': '2024021001340070700_r21'}

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 9:48 p.m.)
Indexed	1 month, 2 weeks ago (July 8, 2025, 6:26 a.m.)
Issued	40 years, 7 months ago (Jan. 1, 1985)
Published	40 years, 7 months ago (Jan. 1, 1985)
Published Print	40 years, 7 months ago (Jan. 1, 1985)

Funders 0

None

BibTeX

@article{Alba_1985, title={Reduction into a rational fraction of a thermodynamic property of the liquid state: Experimental determinations in the case of CO2 and n-butane. Extension to the other properties}, volume={82}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.448757}, DOI={10.1063/1.448757}, number={1}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Alba, Christiane and Ter Minassian, Léon and Denis, Armelle and Soulard, Alain}, year={1985}, month=jan, pages={384–393} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        8
      ]
    ],
    "date-time": "2025-07-08T10:26:43Z",
    "timestamp": 1751970403910
  },
  "reference-count": 21,
  "publisher": "AIP Publishing",
  "issue": "1",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1985,
        1,
        1
      ]
    ]
  },
  "abstract": "<jats:p>The expansivity of liquid CO2 and of n-butane is determined as a function of pressure up to 4\u2009kbar, from the melting temperatures up to the critical temperatures. The experimental method is piezothermal. The set of data is processed through a fit with a multipoint Pad\u00e9 approximant using an algorithm due to Werner. This particular technique determines, in its reduced form, the unique rational function relevant to the problem. The expansivity of the whole liquid phase is described in terms of a simple equation with four coefficients which enables calculation of the other thermodynamic properties. The general aspect of the phenomenological equations is discussed in this instance, underlining the particular behavior of the heat capacity as a function of pressure.</jats:p>",
  "DOI": "10.1063/1.448757",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T13:00:36Z",
    "timestamp": 1027688436000
  },
  "page": "384-393",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 43,
  "title": "Reduction into a rational fraction of a thermodynamic property of the liquid state: Experimental determinations in the case of CO2 and <i>n</i>-butane. Extension to the other properties",
  "prefix": "10.1063",
  "volume": "82",
  "author": [
    {
      "given": "Christiane",
      "family": "Alba",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Laboratoire de Chimie Physique, 11 Rue Pierre et Marie Curie, 75231 Paris Cedex 05, France"
        }
      ]
    },
    {
      "given": "L\u00e9on",
      "family": "Ter Minassian",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratoire de Chimie Physique, 11 Rue Pierre et Marie Curie, 75231 Paris Cedex 05, France"
        }
      ]
    },
    {
      "given": "Armelle",
      "family": "Denis",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratoire de Chimie Quantique (Universit\u00e9 de Paris VI), Institut de Biologie Physico Chimique, 13 Rue Pierre et Marie Curie, Paris, France"
        }
      ]
    },
    {
      "given": "Alain",
      "family": "Soulard",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Laboratoire de Min\u00e9ralogie et de Cristallographie, Universit\u00e9 Pierre et Marie Curie, 4 Place Jussieu, 75230 Paris Cedex 05, France"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024021001340070700_r1",
      "doi-asserted-by": "crossref",
      "first-page": "3",
      "DOI": "10.2307/20025445",
      "volume": "49",
      "year": "1913",
      "journal-title": "Proc. Am. Acad. Arts Sci."
    },
    {
      "key": "2024021001340070700_r2",
      "doi-asserted-by": "crossref",
      "first-page": "1199",
      "DOI": "10.1016/0021-9614(74)90159-1",
      "volume": "6",
      "year": "1974",
      "journal-title": "J. Chem. Thermodyn."
    },
    {
      "key": "2024021001340070700_r3",
      "doi-asserted-by": "crossref",
      "first-page": "265",
      "DOI": "10.1051/jcp/1970670265",
      "volume": "67",
      "year": "1970",
      "journal-title": "J. Chim. Phys."
    },
    {
      "key": "2024021001340070700_r4",
      "doi-asserted-by": "crossref",
      "first-page": "3064",
      "DOI": "10.1063/1.442402",
      "volume": "75",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001340070700_r5",
      "doi-asserted-by": "crossref",
      "first-page": "450",
      "DOI": "10.1088/0022-3735/16/5/019",
      "volume": "16",
      "year": "1983",
      "journal-title": "J. Phys. E"
    },
    {
      "key": "2024021001340070700_r6",
      "first-page": "257",
      "volume": "76",
      "year": "1979",
      "journal-title": "Lectures Notes Math."
    },
    {
      "key": "2024021001340070700_r7",
      "doi-asserted-by": "crossref",
      "first-page": "375",
      "DOI": "10.1016/0021-9614(77)90059-3",
      "volume": "9",
      "year": "1977",
      "journal-title": "J. Chem. Thermodyn."
    },
    {
      "key": "2024021001340070700_r8"
    },
    {
      "key": "2024021001340070700_r9"
    },
    {
      "key": "2024021001340070700_r10"
    },
    {
      "key": "2024021001340070700_r11"
    },
    {
      "key": "2024021001340070700_r12",
      "volume": "169",
      "year": "1982",
      "journal-title": "NBS Monogr."
    },
    {
      "issue": "1",
      "key": "2024021001340070700_r13",
      "first-page": "33",
      "volume": "16",
      "year": "1971",
      "journal-title": "Sov. Phys. Dokl."
    },
    {
      "key": "2024021001340070700_r14",
      "doi-asserted-by": "crossref",
      "first-page": "4721",
      "DOI": "10.1021/ja00406a010",
      "volume": "103",
      "year": "1981",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "2024021001340070700_r15",
      "first-page": "120",
      "volume": "18",
      "year": "1971",
      "journal-title": "Therm. Eng. (USSR)"
    },
    {
      "key": "2024021001340070700_r16",
      "first-page": "115",
      "volume": "72",
      "year": "1974",
      "journal-title": "Physical"
    },
    {
      "key": "2024021001340070700_r17",
      "doi-asserted-by": "crossref",
      "first-page": "3002",
      "DOI": "10.1021/j100212a038",
      "volume": "86",
      "year": "1982",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021001340070700_r18",
      "doi-asserted-by": "crossref",
      "first-page": "129",
      "DOI": "10.2307/20023533",
      "volume": "77",
      "year": "1949",
      "journal-title": "Proc. Am. Acad. Arts Sci."
    },
    {
      "key": "2024021001340070700_r19",
      "doi-asserted-by": "crossref",
      "first-page": "1429",
      "DOI": "10.1080/00268977900101051",
      "volume": "37",
      "year": "1979",
      "journal-title": "Mol. Phys."
    },
    {
      "key": "2024021001340070700_r20",
      "doi-asserted-by": "crossref",
      "first-page": "59",
      "DOI": "10.1016/0031-8914(74)90081-0",
      "volume": "76",
      "year": "1974",
      "journal-title": "Physica"
    },
    {
      "key": "2024021001340070700_r21"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/82/1/384/18951215/384_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/82/1/384/18951215/384_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T02:48:40Z",
    "timestamp": 1707533320000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/82/1/384/218943/Reduction-into-a-rational-fraction-of-a"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1985,
        1,
        1
      ]
    ]
  },
  "references-count": 21,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1985,
          1,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.448757",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1985,
        1,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1985,
        1,
        1
      ]
    ]
  }
}