DOI: 10.1063/1.448434. Use of carbon–carbon nuclear spin diffusion for the study of the miscibility of polymer blends

Use of carbon–carbon nuclear spin diffusion for the study of the miscibility of polymer blends

10.1063/1.448434

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

This high-resolution solid-state NMR work explores the usefulness of carbon–carbon nuclear spin diffusion to probe the miscibility of polymer blends. Experiments involving one- and two-dimensional NMR spectra, applied to blends of poly(ethylene terephthalate) (PET) and bisphenol-A polycarbonate (BPAPC), show that spin exchange occurs between carbon-13 nuclei located in monomer units that belong to the two different homopolymers. Carbon spin diffusion, which strongly depends on the internuclear distance, is explored as a possible probe for specific interactions between polar groups of the two polymers. Our results clearly show that the PET/BPAPC blends studied are homogeneously mixed at distances of 4.5 to 6 Å.

Bibliography

Linder, M., Henrichs, P. M., Hewitt, J. M., & Massa, D. J. (1985). Use of carbonâcarbon nuclear spin diffusion for the study of the miscibility of polymer blends. The Journal of Chemical Physics, 82(3), 1585â1598.

Authors 4

Max Linder (first)
P. Mark Henrichs (additional)
J. Michael Hewitt (additional)
Dennis J. Massa (additional)

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Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 9:53 p.m.)
Indexed	2 months ago (June 26, 2025, 9:09 a.m.)
Issued	40 years, 6 months ago (Feb. 1, 1985)
Published	40 years, 6 months ago (Feb. 1, 1985)
Published Print	40 years, 6 months ago (Feb. 1, 1985)

Funders 0

None

BibTeX

@article{Linder_1985, title={Use of carbon–carbon nuclear spin diffusion for the study of the miscibility of polymer blends}, volume={82}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.448434}, DOI={10.1063/1.448434}, number={3}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Linder, Max and Henrichs, P. Mark and Hewitt, J. Michael and Massa, Dennis J.}, year={1985}, month=feb, pages={1585–1598} }

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