DOI: 10.1063/1.448246. Dynamics of intramolecular vibrational-energy redistribution (IVR). I. Coherence effects

Dynamics of intramolecular vibrational-energy redistribution (IVR). I. Coherence effects

10.1063/1.448246

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

In this series of papers, theoretical and experimental results concerning the dynamical manifestations of intramolecular vibrational-energy redistribution (IVR) in temporally resolved fluorescence are presented. In this paper (I) we present a general treatment of IVR and coherence effects in multilevel vibrational systems. Specifically, the concern is with the derivation of the characteristics of the beat-modulated fluorescence decays which arise from vibrational coupling among N levels within a molecule. Relations connecting quantum beat frequencies, phases, and modulation depths to coupling parameters are presented. Likely sources of deviation of experimental results from theoretical predictions are considered. And, finally, the direct link between IVR and time-resolved fluorescence experiments is discussed with emphasis placed on the physical interpretation of vibrational quantum beats and the nature of IVR as a function of vibrational energy in a molecule.

Bibliography

Felker, P. M., & Zewail, A. H. (1985). Dynamics of intramolecular vibrational-energy redistribution (IVR). I. Coherence effects. The Journal of Chemical Physics, 82(7), 2961â2974.

Authors 2

Peter M. Felker (first)
Ahmed H. Zewail (additional)

References 31 Referenced 152

10.1039/dc9837500007 / Faraday Discuss. Chem. Soc. (1983)
{'key': '2024021001535061500_r2'}
{'key': '2024021001535061500_r3', 'first-page': '113', 'volume': '102', 'year': '1984', 'journal-title': 'Chem. Phys. Lett.'} / Chem. Phys. Lett. (1984)
10.1103/PhysRevLett.53.501 / Phys. Rev. Lett. (1984)
10.1016/0009-2614(84)85196-9 / Chem. Phys. Lett. (1984)
10.1063/1.448247 / J. Chem. Phys. (1985)
10.1063/1.448248 / J. Chem. Phys. (1985)
10.1063/1.448249 / J. Chem. Phys. (1985)
{'key': '2024021001535061500_r9'}
{'key': '2024021001535061500_r10'}
{'key': '2024021001535061500_r11'}
10.1063/1.447922 / J. Chem. Phys. (1984)
10.1080/00268976900100861 / Mol. Phys. (1969)
10.1103/PhysRevLett.32.1333 / Phys. Rev. Lett. (1974)
10.1063/1.446227 / J. Chem. Phys. (1983)
10.1063/1.440850 / J. Chem. Phys. (1981)
{'key': '2024021001535061500_r15'}
10.1080/01406568008070155 / Mol. Cryst. Liq. Cryst. (1980)
10.1016/0301-0104(74)80032-7 / Chem. Phys. (1974)
{'key': '2024021001535061500_r15c'}
{'key': '2024021001535061500_r16'}
{'key': '2024021001535061500_r17'}
10.1016/0301-0104(84)85187-3 / Chem. Phys. (1984)
10.1063/1.447051 / J. Chem. Phys. (1984)
{'key': '2024021001535061500_r18b'}
10.1063/1.437629 / J. Chem. Phys. (1979)
{'key': '2024021001535061500_r19a', 'first-page': '3475', 'volume': '74', 'year': '1981', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1981)
{'key': '2024021001535061500_r19b', 'first-page': '61', 'volume': '97', 'year': '1983', 'journal-title': 'Chem. Phys. Lett.'} / Chem. Phys. Lett. (1983)
10.1063/1.447923 / J. Phys. Chem. (1984)
10.1063/1.1680921 / J. Chem. Phys. (1974)
10.1016/0301-0104(76)80038-9 / Chem. Phys. (1976)

Dates

Type	When
Created	23 years, 1 month ago (July 26, 2002, 9:08 a.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 10:07 p.m.)
Indexed	1 month ago (Aug. 6, 2025, 9 a.m.)
Issued	40 years, 5 months ago (April 1, 1985)
Published	40 years, 5 months ago (April 1, 1985)
Published Print	40 years, 5 months ago (April 1, 1985)

Funders 0

None

BibTeX

@article{Felker_1985, title={Dynamics of intramolecular vibrational-energy redistribution (IVR). I. Coherence effects}, volume={82}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.448246}, DOI={10.1063/1.448246}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Felker, Peter M. and Zewail, Ahmed H.}, year={1985}, month=apr, pages={2961–2974} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        6
      ]
    ],
    "date-time": "2025-08-06T13:00:43Z",
    "timestamp": 1754485243304
  },
  "reference-count": 31,
  "publisher": "AIP Publishing",
  "issue": "7",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1985,
        4,
        1
      ]
    ]
  },
  "abstract": "<jats:p>In this series of papers, theoretical and experimental results concerning the dynamical manifestations of intramolecular vibrational-energy redistribution (IVR) in temporally resolved fluorescence are presented. In this paper (I) we present a general treatment of IVR and coherence effects in multilevel vibrational systems. Specifically, the concern is with the derivation of the characteristics of the beat-modulated fluorescence decays which arise from vibrational coupling among N levels within a molecule. Relations connecting quantum beat frequencies, phases, and modulation depths to coupling parameters are presented. Likely sources of deviation of experimental results from theoretical predictions are considered. And, finally, the direct link between IVR and time-resolved fluorescence experiments is discussed with emphasis placed on the physical interpretation of vibrational quantum beats and the nature of IVR as a function of vibrational energy in a molecule.</jats:p>",
  "DOI": "10.1063/1.448246",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2002,
        7,
        26
      ]
    ],
    "date-time": "2002-07-26T13:08:03Z",
    "timestamp": 1027688883000
  },
  "page": "2961-2974",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 152,
  "title": "Dynamics of intramolecular vibrational-energy redistribution (IVR). I. Coherence effects",
  "prefix": "10.1063",
  "volume": "82",
  "author": [
    {
      "given": "Peter M.",
      "family": "Felker",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Arthur Amos Noyes Laboratory of Chemical Physics,"
        }
      ]
    },
    {
      "given": "Ahmed H.",
      "family": "Zewail",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Arthur Amos Noyes Laboratory of Chemical Physics,"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024021001535061500_r1",
      "doi-asserted-by": "crossref",
      "first-page": "7",
      "DOI": "10.1039/dc9837500007",
      "volume": "75",
      "year": "1983",
      "journal-title": "Faraday Discuss. Chem. Soc."
    },
    {
      "key": "2024021001535061500_r2"
    },
    {
      "key": "2024021001535061500_r3",
      "first-page": "113",
      "volume": "102",
      "year": "1984",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021001535061500_r4",
      "doi-asserted-by": "crossref",
      "first-page": "501",
      "DOI": "10.1103/PhysRevLett.53.501",
      "volume": "53",
      "year": "1984",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024021001535061500_r5",
      "doi-asserted-by": "crossref",
      "first-page": "303",
      "DOI": "10.1016/0009-2614(84)85196-9",
      "volume": "108",
      "year": "1984",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021001535061500_r6",
      "doi-asserted-by": "crossref",
      "first-page": "2975",
      "DOI": "10.1063/1.448247",
      "volume": "82",
      "year": "1985",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r7",
      "doi-asserted-by": "crossref",
      "first-page": "2994",
      "DOI": "10.1063/1.448248",
      "volume": "82",
      "year": "1985",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r8",
      "doi-asserted-by": "crossref",
      "first-page": "3003",
      "DOI": "10.1063/1.448249",
      "volume": "82",
      "year": "1985",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r9"
    },
    {
      "key": "2024021001535061500_r10"
    },
    {
      "key": "2024021001535061500_r11"
    },
    {
      "key": "2024021001535061500_r12",
      "doi-asserted-by": "crossref",
      "first-page": "2195",
      "DOI": "10.1063/1.447922",
      "volume": "81",
      "year": "1984",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r13",
      "doi-asserted-by": "crossref",
      "first-page": "109",
      "DOI": "10.1080/00268976900100861",
      "volume": "17",
      "year": "1969",
      "journal-title": "Mol. Phys."
    },
    {
      "key": "2024021001535061500_r13a",
      "doi-asserted-by": "crossref",
      "first-page": "1333",
      "DOI": "10.1103/PhysRevLett.32.1333",
      "volume": "32",
      "year": "1974",
      "journal-title": "Phys. Rev. Lett."
    },
    {
      "key": "2024021001535061500_r14",
      "doi-asserted-by": "crossref",
      "first-page": "3190",
      "DOI": "10.1063/1.446227",
      "volume": "79",
      "year": "1983",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r14a",
      "doi-asserted-by": "crossref",
      "first-page": "43",
      "DOI": "10.1063/1.440850",
      "volume": "74",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r15"
    },
    {
      "key": "2024021001535061500_r15a",
      "doi-asserted-by": "crossref",
      "first-page": "121",
      "DOI": "10.1080/01406568008070155",
      "volume": "58",
      "year": "1980",
      "journal-title": "Mol. Cryst. Liq. Cryst."
    },
    {
      "key": "2024021001535061500_r15b",
      "doi-asserted-by": "crossref",
      "first-page": "34",
      "DOI": "10.1016/0301-0104(74)80032-7",
      "volume": "6",
      "year": "1974",
      "journal-title": "Chem. Phys."
    },
    {
      "key": "2024021001535061500_r15c"
    },
    {
      "key": "2024021001535061500_r16"
    },
    {
      "key": "2024021001535061500_r17"
    },
    {
      "key": "2024021001535061500_r18",
      "doi-asserted-by": "crossref",
      "first-page": "375",
      "DOI": "10.1016/0301-0104(84)85187-3",
      "volume": "84",
      "year": "1984",
      "journal-title": "Chem. Phys."
    },
    {
      "key": "2024021001535061500_r18a",
      "doi-asserted-by": "crossref",
      "first-page": "2578",
      "DOI": "10.1063/1.447051",
      "volume": "80",
      "year": "1984",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r18b"
    },
    {
      "key": "2024021001535061500_r19",
      "doi-asserted-by": "crossref",
      "first-page": "2018",
      "DOI": "10.1063/1.437629",
      "volume": "70",
      "year": "1979",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r19a",
      "first-page": "3475",
      "volume": "74",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r19b",
      "first-page": "61",
      "volume": "97",
      "year": "1983",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021001535061500_r19c",
      "doi-asserted-by": "crossref",
      "first-page": "2209",
      "DOI": "10.1063/1.447923",
      "volume": "81",
      "year": "1984",
      "journal-title": "J. Phys. Chem."
    },
    {
      "key": "2024021001535061500_r20",
      "doi-asserted-by": "crossref",
      "first-page": "4431",
      "DOI": "10.1063/1.1680921",
      "volume": "60",
      "year": "1974",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001535061500_r21",
      "doi-asserted-by": "crossref",
      "first-page": "189",
      "DOI": "10.1016/0301-0104(76)80038-9",
      "volume": "14",
      "year": "1976",
      "journal-title": "Chem. Phys."
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/82/7/2961/18952588/2961_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/82/7/2961/18952588/2961_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T03:07:48Z",
    "timestamp": 1707534468000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/82/7/2961/791209/Dynamics-of-intramolecular-vibrational-energy"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1985,
        4,
        1
      ]
    ]
  },
  "references-count": 31,
  "journal-issue": {
    "issue": "7",
    "published-print": {
      "date-parts": [
        [
          1985,
          4,
          1
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.448246",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1985,
        4,
        1
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1985,
        4,
        1
      ]
    ]
  }
}