DOI: 10.1063/1.448070. FTIR spectra of (HF)<i>n</i> species in solid neon

FTIR spectra of (HF)n species in solid neon

10.1063/1.448070

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Condensation of Ne/HF mixtures at 5 K produces in addition to monomer HF numerous strong, sharp infrared absorptions in the 4000–3600 and 600–300 cm−1 regions and broader bands in the 3500–3100 and 1300–600 cm−1 regions. The relative absorbances of these bands depend upon concentration, spray-on rate, and sample annealing, which are used to identify individual (HF)n species. Sharp bands at 3919, 3848, and 410 cm−1 are assigned to (HF)2. Further infrared evidence is presented for an open chain (HF)3 species. The broader bands assigned to cyclic-(HF)n species increase at the expense of the sharper bands under conditions which favor association of HF in the matrix.

Bibliography

Andrews, L., Bondybey, V. E., & English, J. H. (1984). FTIR spectra of (HF)n species in solid neon. The Journal of Chemical Physics, 81(8), 3452â3457.

Authors 3

Lester Andrews (first)
V. E. Bondybey (additional)
J. H. English (additional)

References 20 Referenced 56

10.1063/1.1677553 / J. Chem. Phys. (1972)
10.1063/1.1744342 / J. Chem. Phys. (1958)
10.1016/0022-2852(59)90042-6 / J. Mol. Spectrosc. (1959)
10.1051/jcp/196966s21309 / J. Chim. Phys. (1969)
10.1063/1.442593 / J. Chem. Phys. (1981)
10.1016/0009-2614(83)80478-3 / Chem. Phys. Lett. (1983)
{'key': '2024021001135047900_r7'}
10.1063/1.445078 / J. Chem. Phys. (1983)
{'key': '2024021001135047900_r9'}
10.1063/1.1728120 / J. Chem. Phys. (1966)
10.1063/1.1675371 / J. Chem. Phys. (1971)
{'key': '2024021001135047900_r12', 'first-page': '1429', 'volume': '48', 'year': '1968', 'journal-title': 'J. Chem. Phys.'} / J. Chem. Phys. (1968)
10.1016/0022-2852(76)90376-3 / J. Mol. Spectrosc. (1976)
10.1080/01442358109353322 / Int. Rev. Phys. Chem. (1981)
{'key': '2024021001135047900_r15'}
10.1063/1.446994 / J. Chem. Phys. (1984)
10.1063/1.1676408 / J. Chem. Phys. (1971)
10.1063/1.446093 / J. Chem. Phys. (1983)
10.1063/1.446286 / J. Chem. Phys. (1983)
10.1098/rspa.1975.0120 / Proc. R. Soc. London Ser. A (1975)

Dates

Type	When
Created	22 years, 6 months ago (Feb. 28, 2003, 12:34 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 9:28 p.m.)
Indexed	4 months, 4 weeks ago (April 8, 2025, 7:06 a.m.)
Issued	40 years, 10 months ago (Oct. 15, 1984)
Published	40 years, 10 months ago (Oct. 15, 1984)
Published Print	40 years, 10 months ago (Oct. 15, 1984)

Funders 0

None

BibTeX

@article{Andrews_1984, title={FTIR spectra of (HF)n species in solid neon}, volume={81}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.448070}, DOI={10.1063/1.448070}, number={8}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Andrews, Lester and Bondybey, V. E. and English, J. H.}, year={1984}, month=oct, pages={3452–3457} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        4,
        8
      ]
    ],
    "date-time": "2025-04-08T11:06:53Z",
    "timestamp": 1744110413689
  },
  "reference-count": 20,
  "publisher": "AIP Publishing",
  "issue": "8",
  "content-domain": {
    "domain": [
      "pubs.aip.org"
    ],
    "crossmark-restriction": true
  },
  "published-print": {
    "date-parts": [
      [
        1984,
        10,
        15
      ]
    ]
  },
  "abstract": "<jats:p>Condensation of Ne/HF mixtures at 5 K produces in addition to monomer HF numerous strong, sharp infrared absorptions in the 4000\u20133600 and 600\u2013300 cm\u22121 regions and broader bands in the 3500\u20133100 and 1300\u2013600 cm\u22121 regions. The relative absorbances of these bands depend upon concentration, spray-on rate, and sample annealing, which are used to identify individual (HF)n species. Sharp bands at 3919, 3848, and 410 cm\u22121 are assigned to (HF)2. Further infrared evidence is presented for an open chain (HF)3 species. The broader bands assigned to cyclic-(HF)n species increase at the expense of the sharper bands under conditions which favor association of HF in the matrix.</jats:p>",
  "DOI": "10.1063/1.448070",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2003,
        2,
        28
      ]
    ],
    "date-time": "2003-02-28T17:34:05Z",
    "timestamp": 1046453645000
  },
  "page": "3452-3457",
  "update-policy": "http://dx.doi.org/10.1063/aip-crossmark-policy-page",
  "source": "Crossref",
  "is-referenced-by-count": 56,
  "title": "FTIR spectra of (HF)<i>n</i> species in solid neon",
  "prefix": "10.1063",
  "volume": "81",
  "author": [
    {
      "given": "Lester",
      "family": "Andrews",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Department of Chemistry, University of Virginia, Charlottesville, Virginia 22901"
        }
      ]
    },
    {
      "given": "V. E.",
      "family": "Bondybey",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "AT&T Bell Laboratories, Murray Hill, New Jersey 07974"
        }
      ]
    },
    {
      "given": "J. H.",
      "family": "English",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "AT&T Bell Laboratories, Murray Hill, New Jersey 07974"
        }
      ]
    }
  ],
  "member": "317",
  "reference": [
    {
      "key": "2024021001135047900_r1",
      "doi-asserted-by": "crossref",
      "first-page": "2442",
      "DOI": "10.1063/1.1677553",
      "volume": "56",
      "year": "1972",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r2",
      "doi-asserted-by": "crossref",
      "first-page": "1040",
      "DOI": "10.1063/1.1744342",
      "volume": "28",
      "year": "1958",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r3",
      "doi-asserted-by": "crossref",
      "first-page": "473",
      "DOI": "10.1016/0022-2852(59)90042-6",
      "volume": "3",
      "year": "1959",
      "journal-title": "J. Mol. Spectrosc."
    },
    {
      "key": "2024021001135047900_r4",
      "doi-asserted-by": "crossref",
      "first-page": "1309",
      "DOI": "10.1051/jcp/196966s21309",
      "volume": "66",
      "year": "1969",
      "journal-title": "J. Chim. Phys."
    },
    {
      "key": "2024021001135047900_r5",
      "doi-asserted-by": "crossref",
      "first-page": "4733",
      "DOI": "10.1063/1.442593",
      "volume": "75",
      "year": "1981",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r6",
      "doi-asserted-by": "crossref",
      "first-page": "133",
      "DOI": "10.1016/0009-2614(83)80478-3",
      "volume": "96",
      "year": "1983",
      "journal-title": "Chem. Phys. Lett."
    },
    {
      "key": "2024021001135047900_r7"
    },
    {
      "key": "2024021001135047900_r8",
      "doi-asserted-by": "crossref",
      "first-page": "2154",
      "DOI": "10.1063/1.445078",
      "volume": "78",
      "year": "1983",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r9"
    },
    {
      "key": "2024021001135047900_r10",
      "doi-asserted-by": "crossref",
      "first-page": "3399",
      "DOI": "10.1063/1.1728120",
      "volume": "45",
      "year": "1966",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r11",
      "doi-asserted-by": "crossref",
      "first-page": "3491",
      "DOI": "10.1063/1.1675371",
      "volume": "54",
      "year": "1971",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r12",
      "first-page": "1429",
      "volume": "48",
      "year": "1968",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r13",
      "doi-asserted-by": "crossref",
      "first-page": "1",
      "DOI": "10.1016/0022-2852(76)90376-3",
      "volume": "61",
      "year": "1976",
      "journal-title": "J. Mol. Spectrosc."
    },
    {
      "key": "2024021001135047900_r14",
      "doi-asserted-by": "crossref",
      "first-page": "253",
      "DOI": "10.1080/01442358109353322",
      "volume": "1",
      "year": "1981",
      "journal-title": "Int. Rev. Phys. Chem."
    },
    {
      "key": "2024021001135047900_r15"
    },
    {
      "key": "2024021001135047900_r16",
      "doi-asserted-by": "crossref",
      "first-page": "2446",
      "DOI": "10.1063/1.446994",
      "volume": "80",
      "year": "1984",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r17",
      "doi-asserted-by": "crossref",
      "first-page": "2296",
      "DOI": "10.1063/1.1676408",
      "volume": "55",
      "year": "1971",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r18",
      "doi-asserted-by": "crossref",
      "first-page": "2488",
      "DOI": "10.1063/1.446093",
      "volume": "79",
      "year": "1983",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r19",
      "doi-asserted-by": "crossref",
      "first-page": "3670",
      "DOI": "10.1063/1.446286",
      "volume": "79",
      "year": "1983",
      "journal-title": "J. Chem. Phys."
    },
    {
      "key": "2024021001135047900_r20",
      "doi-asserted-by": "crossref",
      "first-page": "579",
      "DOI": "10.1098/rspa.1975.0120",
      "volume": "344",
      "year": "1975",
      "journal-title": "Proc. R. Soc. London Ser. A"
    }
  ],
  "container-title": "The Journal of Chemical Physics",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/81/8/3452/18949847/3452_1_online.pdf",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "syndication"
    },
    {
      "URL": "https://pubs.aip.org/aip/jcp/article-pdf/81/8/3452/18949847/3452_1_online.pdf",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        2,
        10
      ]
    ],
    "date-time": "2024-02-10T02:28:14Z",
    "timestamp": 1707532094000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://pubs.aip.org/jcp/article/81/8/3452/565401/FTIR-spectra-of-HF-n-species-in-solid-neonFTIR"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1984,
        10,
        15
      ]
    ]
  },
  "references-count": 20,
  "journal-issue": {
    "issue": "8",
    "published-print": {
      "date-parts": [
        [
          1984,
          10,
          15
        ]
      ]
    }
  },
  "URL": "http://dx.doi.org/10.1063/1.448070",
  "relation": {},
  "ISSN": [
    "0021-9606",
    "1089-7690"
  ],
  "subject": [],
  "published-other": {
    "date-parts": [
      [
        1984,
        10,
        15
      ]
    ]
  },
  "published": {
    "date-parts": [
      [
        1984,
        10,
        15
      ]
    ]
  }
}