DOI: 10.1063/1.447087. Statistical thermodynamics of polydisperse fluids [Penn]

Statistical thermodynamics of polydisperse fluids

10.1063/1.447087

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

The statistical mechanical formalisms for dealing with mixtures containing an infinite number of components are discussed. The partition function and the thermodynamic properties can be easily generalized from the corresponding results for pure substances when the polydisperse fluid is studied in a four-dimensional space. The chemical potential field acts along the additional coordinate: the composition axis. A perturbation theory for narrow distributions is developed. A small parameter measuring the width of the chemical potential function is used within a semigrand ensemble. An equivalent, hybrid expansion expresses the results in terms of the variance of the composition distribution.

Bibliography

Briano, J. G., & Glandt, E. D. (1984). Statistical thermodynamics of polydisperse fluids. The Journal of Chemical Physics, 80(7), 3336â3343.

Authors 2

J. G. Briano (first)
E. D. Glandt (additional)

References 33 Referenced 105

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{'key': '2024021000453474200_r6'}
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{'key': '2024021000453474200_r7c', 'first-page': '46', 'volume': '48', 'year': '1952'} (1952)
{'key': '2024021000453474200_r7d', 'first-page': '69', 'volume': '49', 'year': '1953', 'journal-title': 'Chem. Eng. Prog. Symp. Ser.'} / Chem. Eng. Prog. Symp. Ser. (1953)
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{'key': '2024021000453474200_r9', 'first-page': '163', 'volume': '55', 'year': '1976', 'journal-title': 'Hydrocarbon Process.'} / Hydrocarbon Process. (1976)
{'key': '2024021000453474200_r10'}
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{'key': '2024021000453474200_r13'}
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Dates

Type	When
Created	22 years, 5 months ago (Feb. 28, 2003, 12:18 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 9:05 p.m.)
Indexed	3 weeks, 5 days ago (Aug. 2, 2025, 1:28 a.m.)
Issued	41 years, 4 months ago (April 1, 1984)
Published	41 years, 4 months ago (April 1, 1984)
Published Print	41 years, 4 months ago (April 1, 1984)

Funders 0

None

BibTeX

@article{Briano_1984, title={Statistical thermodynamics of polydisperse fluids}, volume={80}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.447087}, DOI={10.1063/1.447087}, number={7}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Briano, J. G. and Glandt, E. D.}, year={1984}, month=apr, pages={3336–3343} }

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