DOI: 10.1063/1.446859. Multiple nucleation pathways near triple points of Ar

Multiple nucleation pathways near triple points of Ar–Kr mixtures

10.1063/1.446859

Crossref journal-article

AIP Publishing

The Journal of Chemical Physics (317)

Abstract

Cluster partition functions for droplets of Ar–Kr mixtures are evaluated at 90 and 120 K by the inversely restricted sampling (IRS) algorithm. These quantities and series expansion techniques are used within the droplet model to condensation to predict the condensation curve in the neighborhood of a triple point of the Ar–Kr phase diagrams. Using the same series, the free energy surface for droplet growth is examined for supersaturated states of the mixture. For strongly supersaturated states in the neighborhood of the triple point, we find two saddle-point free energy barriers. It is suggested that these physical circumstances provide a sensitive testing ground for molecular theories of homogeneous nucleation.

Bibliography

Phillips, P., LaViolette, R. A., & Pratt, L. R. (1984). Multiple nucleation pathways near triple points of ArâKr mixtures. The Journal of Chemical Physics, 80(4), 1605â1609.

Authors 3

Philip Phillips (first)
Randall A. LaViolette (additional)
Lawrence R. Pratt (additional)

References 17 Referenced 9

{'key': '2024021000230052800_r1'}
10.1016/0003-4916(67)90200-X / Ann. Phys. (1967)
10.1016/0003-4916(69)90153-5 / Ann. Phys. (1969)
{'key': '2024021000230052800_r3'}
{'key': '2024021000230052800_r4'}
10.1175/1520-0469(1980)037<2508:ASOHCF>2.0.CO;2 / J. At. Sci. (1980)
{'key': '2024021000230052800_r5a'}
10.1111/j.1151-2916.1969.tb11194.x / J. Am. Ceram. Soc. (1969)
10.1103/PhysRevA.28.2482 / Phys. Rev. A (1983)
10.1063/1.443874 / J. Chem. Phys. (1982)
{'key': '2024021000230052800_r8'}
{'key': '2024021000230052800_r9', 'first-page': '255', 'volume': '3', 'year': '1967', 'journal-title': 'Physics (NY)'} / Physics (NY) (1967)
10.1103/PhysRevLett.47.1921 / Phys. Rev. Lett. (1981)
10.1002/9780470142592.ch2 / Adv. Chem. Phys. (1979)
10.1103/PhysRev.184.151 / Phys. Rev. (1969)
{'key': '2024021000230052800_r12'}
{'key': '2024021000230052800_r13'}

Dates

Type	When
Created	22 years, 5 months ago (Feb. 28, 2003, 12:18 p.m.)
Deposited	1 year, 6 months ago (Feb. 9, 2024, 8:45 p.m.)
Indexed	1 year, 6 months ago (Feb. 10, 2024, 4:20 a.m.)
Issued	41 years, 6 months ago (Feb. 15, 1984)
Published	41 years, 6 months ago (Feb. 15, 1984)
Published Print	41 years, 6 months ago (Feb. 15, 1984)

Funders 0

None

BibTeX

@article{Phillips_1984, title={Multiple nucleation pathways near triple points of Ar–Kr mixtures}, volume={80}, ISSN={1089-7690}, url={http://dx.doi.org/10.1063/1.446859}, DOI={10.1063/1.446859}, number={4}, journal={The Journal of Chemical Physics}, publisher={AIP Publishing}, author={Phillips, Philip and LaViolette, Randall A. and Pratt, Lawrence R.}, year={1984}, month=feb, pages={1605–1609} }

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